The electron moves in a circular orbit around the nucleus, creating a loop current.
The current \( I \) is:
\[ I = \frac{\text{Charge per revolution}}{\text{Time for one revolution}} \]
The charge of an electron is \( e \) and time period \( T \) is:
\[ T = \frac{2\pi r}{v} \]
Thus,
\[ I = \frac{e}{T} = \frac{e}{\frac{2\pi r}{v}} = \frac{ev}{2\pi r} \]
The magnetic moment \( \mu \) is given by:
\[ \mu = I \times A \]
Since the electron follows a circular path, the area is:
\[ A = \pi r^2 \]
Thus,
\[ \mu = \frac{ev}{2\pi r} \times \pi r^2 \]
\[ \mu = \frac{evr}{2} \]
The angular momentum of the electron is:
\[ L = mvr \]
where \( m \) is the mass of the electron.
Since:
\[ \mu = \frac{evr}{2} \]
Replacing \( vr \) using \( L \):
\[ \mu = \frac{e}{2m} L \]
Thus, the magnetic moment associated with the electron is:
\[ \mu = \frac{e}{2m} L \]
(b) If \( \vec{L} \) is the angular momentum of the electron, show that:
\[ \vec{\mu} = -\frac{e}{2m} \vec{L} \]
The sum of the spin-only magnetic moment values (in B.M.) of $[\text{Mn}(\text{Br})_6]^{3-}$ and $[\text{Mn}(\text{CN})_6]^{3-}$ is ____.