Question:

Acid D formed in above reaction is :

Updated On: Nov 27, 2024
  • Gluconic acid
  • Succinic acid
  • Oxalic acid
  • Malonic acid
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The Correct Option is B

Solution and Explanation

Step-by-step Reaction Analysis:
1.Reaction of C$_2$H$_5$Br with alcoholic KOH:
C$_2$H$_5$Br (ethyl bromide) undergoes dehydrohalogenation with alcoholic KOH to form ethene (CH$_2$ = CH$_2$).  
This step is represented as:  
\[\text{C}_2\text{H}_5\text{Br} \xrightarrow{\text{alc. KOH}} \text{CH}_2 = \text{CH}_2 \; (\text{A})\]
2. Addition of Br$_2$ in CCl$_4$:
Ethene reacts with bromine (Br$_2$) in the presence of carbon tetrachloride (CCl$_4$) to form 1,2-dibromoethane (BrCH$_2$CH$_2$Br).  
This step is represented as:  
\[\text{CH}_2 = \text{CH}_2 \xrightarrow{\text{Br}_2/\text{CCl}_4} \text{BrCH}_2\text{CH}_2\text{Br} \; (\text{B})\]
3. Reaction of 1,2-dibromoethane with excess KCN:  
The compound BrCH$_2$CH$_2$Br reacts with excess potassium cyanide (KCN) to form 1,2-dicyanoethane (NCCH$_2$CH$_2$CN).  
This step is represented as:  
\[\text{BrCH}_2\text{CH}_2\text{Br} \xrightarrow{\text{Excess KCN}} \text{NCCH}_2\text{CH}_2\text{CN} \; (\text{C})\]
4. Hydrolysis of 1,2-dicyanoethane:
Hydrolysis of 1,2-dicyanoethane (NCCH$_2$CH$_2$CN) in the presence of excess H$_3$O$^+$ (acidic medium) yields succinic acid (HOOCCH$_2$CH$_2$COOH).  
This step is represented as:  
\[\text{NCCH}_2\text{CH}_2\text{CN} \xrightarrow{\text{H}_3\text{O}^+\text{ (Excess)}} \text{HOOCCH}_2\text{CH}_2\text{COOH} \; (\text{D})\]
Conclusion: The acid D formed is succinic acid.

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