The acid formed when propyl magnesium bromide is treated with CO_2 followed by acid hydrolysis is:
C_3H_7OH
Propyl magnesium bromide is a Grignard reagent that reacts with carbon dioxide (CO2) to form a carboxylate anion. This anion is then hydrolyzed to form a carboxylic acid. The reaction can be summarized as follows:
RMgBr + CO2 → RCO− + MgBr+
Upon hydrolysis, the carboxylate anion is converted into a carboxylic acid:
RCO− + H2O → RCOOH
Thus, the acid formed is propionic acid (C3H7COOH), corresponding to option (A).
Propionic acid is the correct product of this Grignard reaction with CO2.
Identify A in the following reaction. 
For the reaction, \(N_{2}O_{4} \rightleftharpoons 2NO_{2}\) graph is plotted as shown below. Identify correct statements.
A. Standard free energy change for the reaction is 5.40 kJ \(mol^{-1}\).
B. As \(\Delta G\) in graph is positive, \(N_{2}O_{4}\) will not dissociate into \(NO_{2}\) at all.
C. Reverse reaction will go to completion.
D. When 1 mole of \(N_{2}O_{4}\) changes into equilibrium mixture, value of \(\Delta G = -0.84 \text{ kJ mol}^{-1}\).
E. When 2 mole of \(NO_{2}\) changes into equilibrium mixture, \(\Delta G\) for equilibrium mixture is \(-6.24 \text{ kJ mol}^{-1}\).
Choose the correct answer from the following.
