
The total work done in a cyclic process is represented by the area enclosed by the graph in a PV diagram. The area can be calculated as the area of the rectangle formed by the points A, B, C, D, and E. The formula to find the work done is given by the area of the graph:
The change in pressure (height) is \( \Delta P = 400 \, \text{kPa} - 100 \, \text{kPa} = 300 \, \text{kPa} = 300 \times 10^3 \, \text{Pa} \).
The change in volume (width) is \( \Delta V = 4 \, \text{m}^3 - 2 \, \text{m}^3 = 2 \, \text{m}^3 \).
The area of a rectangle is \( \text{Area} = \text{height} \times \text{width} \).
Therefore, \( W = \Delta P \times \Delta V = (300 \times 10^3 \, \text{Pa}) \times (2 \, \text{m}^3) = 600 \times 10^3 \, \text{J} = 600 \, \text{kJ} \).
Corrected Calculation:
\(W = (400 - 100) \times 10^3 \, \text{Pa} \times (4 - 2) \, \text{m}^3\)
\(W = 300 \times 10^3 \, \text{Pa} \times 2 \, \text{m}^3\)
\(W = 600 \times 10^3 \, \text{J} = 600 \, \text{kJ}\)
Final Answer: The total work done is 600 kJ.

Match List-I with List-II.
Choose the correct answer from the options given below :
Let \( a \in \mathbb{R} \) and \( A \) be a matrix of order \( 3 \times 3 \) such that \( \det(A) = -4 \) and \[ A + I = \begin{bmatrix} 1 & a & 1 \\ 2 & 1 & 0 \\ a & 1 & 2 \end{bmatrix} \] where \( I \) is the identity matrix of order \( 3 \times 3 \).
If \( \det\left( (a + 1) \cdot \text{adj}\left( (a - 1) A \right) \right) \) is \( 2^m 3^n \), \( m, n \in \{ 0, 1, 2, \dots, 20 \} \), then \( m + n \) is equal to:
Rate law for a reaction between $A$ and $B$ is given by $\mathrm{R}=\mathrm{k}[\mathrm{A}]^{\mathrm{n}}[\mathrm{B}]^{\mathrm{m}}$. If concentration of A is doubled and concentration of B is halved from their initial value, the ratio of new rate of reaction to the initial rate of reaction $\left(\frac{\mathrm{r}_{2}}{\mathrm{r}_{1}}\right)$ is