Given that material P decays into Q, and then Q decays into R, we need to determine the time-dependent mass of P, Q, and R.
1. Decay of P to Q: Let the initial mass of P be \( m_0 \). The mass of P at time \( t \) is given by the exponential decay equation: \[ m_P(t) = m_0 e^{-\lambda_1 t} \] where \( \lambda_1 \) is the decay constant for P. This describes how P decreases over time.
2. Decay of Q to R: The mass of Q at time \( t \) is determined by the difference between the mass of P that has decayed and the mass of Q that has decayed into R.
The mass of Q at any given time is given by: \[ m_Q(t) = \frac{\lambda_1}{\lambda_2 - \lambda_1} m_0 \left(e^{-\lambda_1 t} - e^{-\lambda_2 t}\right) \] where \( \lambda_2 \) is the decay constant for Q.
This equation represents how Q evolves as it decays from P to R.
3. Mass of R: The mass of R at time \( t \) is the remaining mass, which can be expressed as the sum of the mass lost from P and Q: \[ m_R(t) = m_0 - m_P(t) - m_Q(t) \] Substituting the expressions for \( m_P(t) \) and \( m_Q(t) \): \[ m_R(t) = m_0 \left(1 - e^{-\lambda_1 t} - \frac{\lambda_1}{\lambda_2 - \lambda_1} \left(e^{-\lambda_1 t} - e^{-\lambda_2 t}\right)\right) \] This shows how R increases as both P and Q decay.
The correct figure representing the time-dependent mass of P, Q, and R is (2), where:
- The mass of P decreases exponentially.
- The mass of Q initially increases and then decreases as it decays into R.
- The mass of R increases as Q decays.
The wavenumber of the first line (\(n_2 = 3\)) in the Balmer series of hydrogen is \( \overline{\nu}_1 \, \text{cm}^{-1} \). What is the wavenumber (in cm\(^{-1}\)) of the second line (\(n_2 = 4\)) in the Balmer series of He\(^{+}\)?
For the thermal decomposition of \( N_2O_5(g) \) at constant volume, the following table can be formed, for the reaction mentioned below: \[ 2 N_2O_5(g) \rightarrow 2 N_2O_4(g) + O_2(g) \] Given: Rate constant for the reaction is \( 4.606 \times 10^{-2} \text{ s}^{-1} \).
Let \( T_r \) be the \( r^{\text{th}} \) term of an A.P. If for some \( m \), \( T_m = \dfrac{1}{25} \), \( T_{25} = \dfrac{1}{20} \), and \( \displaystyle\sum_{r=1}^{25} T_r = 13 \), then \( 5m \displaystyle\sum_{r=m}^{2m} T_r \) is equal to: