Remember to convert temperatures to Kelvin when working with Carnot engine problems. The efficiency formula relates the temperatures of the hot and cold reservoirs to the engine’s efficiency.
Step 1: Convert Celsius to Kelvin
The temperature of the hot reservoir is given as \( T_H = 99^\circ C \). Convert this to Kelvin:
\[ T_H = 99 + 273 = 372 \, \text{K} \]
Step 2: Use the Carnot Efficiency Formula
The efficiency of a Carnot engine is given by:
\[ \eta = 1 - \frac{T_C}{T_H} \]
where \( T_C \) is the temperature of the cold reservoir and \( T_H \) is the temperature of the hot reservoir.
Step 3: Calculate the Initial Cold Reservoir Temperature
Initially, the efficiency is \( \frac{1}{3} \). So,
\[ \frac{1}{3} = 1 - \frac{T_C}{372} \]
\[ \frac{T_C}{372} = 1 - \frac{1}{3} = \frac{2}{3} \]
\[ T_C = \frac{2}{3} \times 372 = 248 \, \text{K} \]
Step 4: Calculate the Cold Reservoir Temperature After the Increase
When the cold reservoir temperature is increased by \( x \), the new temperature is \( T_C + x \), and the efficiency becomes \( \frac{1}{6} \). So,
\[ \frac{1}{6} = 1 - \frac{T_C + x}{T_H} \]
\[ \frac{T_C + x}{T_H} = 1 - \frac{1}{6} = \frac{5}{6} \]
\[ T_C + x = \frac{5}{6} \times 372 \]
\[ 248 + x = \frac{5}{6} \times 372 \]
Step 5: Solve for \( x \)
\[ 248 + x = 310 \]
\[ x = 310 - 248 = 62 \, \text{K} \]
Conclusion: The value of \( x \) is 62 K (Option 2).
Statement-1: \( \text{ClF}_3 \) has 3 possible structures.
Statement-2: \( \text{III} \) is the most stable structure due to least lone pair-bond pair (lp-bp) repulsion.
Which of the following options is correct?
Given below are two statements: one is labelled as Assertion (A) and the other is labelled as Reason (R).
Assertion (A): Choke coil is simply a coil having a large inductance but a small resistance. Choke coils are used with fluorescent mercury-tube fittings. If household electric power is directly connected to a mercury tube, the tube will be damaged.
Reason (R): By using the choke coil, the voltage across the tube is reduced by a factor \( \frac{R}{\sqrt{R^2 + \omega^2 L^2}} \), where \( \omega \) is the frequency of the supply across resistor \( R \) and inductor \( L \). If the choke coil were not used, the voltage across the resistor would be the same as the applied voltage.
In light of the above statements, choose the most appropriate answer from the options given below:
Thermodynamics in physics is a branch that deals with heat, work and temperature, and their relation to energy, radiation and physical properties of matter.
A thermodynamic system is a specific portion of matter with a definite boundary on which our attention is focused. The system boundary may be real or imaginary, fixed or deformable.
There are three types of systems:
A system undergoes a thermodynamic process when there is some energetic change within the system that is associated with changes in pressure, volume and internal energy.
There are four types of thermodynamic process that have their unique properties, and they are:
The Zeroth law of thermodynamics states that if two bodies are individually in equilibrium with a separate third body, then the first two bodies are also in thermal equilibrium with each other.
The First law of thermodynamics is a version of the law of conservation of energy, adapted for thermodynamic processes, distinguishing three kinds of transfer of energy, as heat, as thermodynamic work, and as energy associated with matter transfer, and relating them to a function of a body's state, called internal energy.
The Second law of thermodynamics is a physical law of thermodynamics about heat and loss in its conversion.
Third law of thermodynamics states, regarding the properties of closed systems in thermodynamic equilibrium: The entropy of a system approaches a constant value when its temperature approaches absolute zero.