The thermal efficiency (\(\eta\)) of a cyclic process, particularly a heat engine, is defined as the ratio of the net work output (\(W_{net}\)) to the heat input (\(Q_{in}\) or \(Q_H\)) from the high-temperature reservoir.
$$ \eta = \frac{W_{net}}{Q_{in}} $$
According to the first law of thermodynamics for a cycle, the net work done equals the net heat transferred: \(W_{net} = Q_{net} = Q_{in} - Q_{out}\), where \(Q_{out}\) (or \(Q_C\)) is the heat rejected to the low-temperature reservoir (magnitude).
Substituting this into the efficiency definition:
$$ \eta = \frac{Q_{in} - Q_{out}}{Q_{in}} = 1 - \frac{Q_{out}}{Q_{in}} $$
This equation relates efficiency to the heat absorbed and rejected during the cycle.
Option (1) represents this fundamental definition of thermal efficiency for a cyclic process operating as a heat engine.
Option (2) is the ideal gas law.
Option (3) relates Gibbs free energy, enthalpy, and entropy.
Option (4) is Newton's second law.