>
IIT JAM CY
List of top Questions asked in IIT JAM CY- 2022
The reaction of 2,4-dinitrofluorobenzene with hydrazine produces a yellow orange solid X used for the identification of an organic functional group G. X and G, respectively, are
IIT JAM CY - 2022
IIT JAM CY
Organic Chemistry
Qualitative Organic Analysis
The ratio of the
2
p
→
1
s
2p → 1s
2
p
→
1
s
transition energy in
H
e
+
He^+
H
e
+
to that in the H atom is closest to
IIT JAM CY - 2022
IIT JAM CY
Physical Chemistry
Atomic Structure
Two close lying bands in a UV spectrum occur at 274 nm and 269 nm. The magnitude of the energy gap between the two bands is ____cm
-1
. (round off to the nearest integer)
IIT JAM CY - 2022
IIT JAM CY
Physical Chemistry
Spectroscopy
At constant temperature, 6.40 g of a substance dissolved in 78 g of benzene decreases the vapor pressure of benzene from 0.125 atm to 0.119 atm. The molar mass of the substance is ____g mol
-1
. (round off to one decimal place)
[Given: Mol. wt. of benzene = 78 g mol
-1
]
IIT JAM CY - 2022
IIT JAM CY
Physical Chemistry
Phase equilibria
The number of
β
\beta
β
particles emitted in the nuclear reaction
238
U
92
→
206
P
b
82
^{238}U_{92} → ^{206}Pb_{82}
238
U
92
→
206
P
b
82
is _______.
IIT JAM CY - 2022
IIT JAM CY
Inorganic Chemistry
Chemical bonding and molecular structure
The number of significant figures in
5.0820
x
1
0
2
5.0820 x 10^2
5.0820
x
1
0
2
is _________.
IIT JAM CY - 2022
IIT JAM CY
Inorganic Chemistry
Analytical Chemistry
The pH of an aqueous buffer prepared using CH3COOH and CH3COO Na
+
is 4.80.
The quantity
[
C
H
3
C
O
O
−
]
−
[
C
H
3
C
O
O
H
]
[
C
H
3
C
O
O
H
]
\frac{[CH_3COO^-]-[CH_3COOH]}{[CH_3COOH]}
[
C
H
3
COO
H
]
[
C
H
3
CO
O
−
]
−
[
C
H
3
COO
H
]
is _____. (round off to three decimal places)
[Given: pK
a
of CH
3
COOH in water is 4.75]
IIT JAM CY - 2022
IIT JAM CY
Physical Chemistry
Chemical equilibria
The d spacing for the first-order X-ray (
λ
\lambda
λ
= 1.54 Å) diffraction event of metallic iron (fcc) at
2
θ
=
20.2
°
2\theta= 20.2°
2
θ
=
20.2°
is _______.Å. (round off to three decimal places)
IIT JAM CY - 2022
IIT JAM CY
Physical Chemistry
Solid State
The B-B bond order in
B
2
B_2
B
2
is ______.
IIT JAM CY - 2022
IIT JAM CY
Inorganic Chemistry
Chemical bonding and molecular structure
An organic compound having molecular formula
C
9
H
10
O
2
C_9H_{10}O_2
C
9
H
10
O
2
exhibits the following spectral characteristics:
′
H
N
M
R
:
δ
9.72
(
t
,
1
H
)
,
7.1
(
d
,
2
H
)
,
6.7
(
d
,
2
H
)
,
3.8
(
s
,
3
H
)
,
3.6
(
d
,
2
H
)
'H NMR: \delta 9.72 (t, 1H), 7.1 (d, 2H), 6.7 (d, 2H), 3.8 (s, 3H), 3.6 (d, 2H)
′
H
NMR
:
δ
9.72
(
t
,
1
H
)
,
7.1
(
d
,
2
H
)
,
6.7
(
d
,
2
H
)
,
3.8
(
s
,
3
H
)
,
3.6
(
d
,
2
H
)
I
R
:
1720
c
m
−
1
IR: ~1720 cm^{-1}
I
R
:
1720
c
m
−
1
The most probable structure of the compound is
IIT JAM CY - 2022
IIT JAM CY
Organic Chemistry
Qualitative Organic Analysis
The compound(s) that participate(s) in Diels-Alder reaction with maleic anhydride is/are
IIT JAM CY - 2022
IIT JAM CY
Organic Chemistry
Reaction Mechanisms & Synthesis
steady current of 1.25 A is passed through an electrochemical cell for 1.5 h using a 12 V battery. The total charge, Q, drawn during this process is __________ Coulombs. (round off to the nearest integer)
IIT JAM CY - 2022
IIT JAM CY
Physical Chemistry
Electrochemistry
Among the following, the suitable route(s) for the conversion of benzaldehyde to acetophenone is/are
IIT JAM CY - 2022
IIT JAM CY
Organic Chemistry
Reaction Mechanisms & Synthesis
The common point defect(s) in a solid is/are
IIT JAM CY - 2022
IIT JAM CY
Physical Chemistry
Solid State
The major product formed in the following reaction is
IIT JAM CY - 2022
IIT JAM CY
Organic Chemistry
Reaction Mechanisms & Synthesis
The conversion of
I
C
l
ICl
I
Cl
to
I
C
l
+
ICl^+
I
C
l
+
involve(s)
IIT JAM CY - 2022
IIT JAM CY
Physical Chemistry
Thermodynamics
The correct statement about the geometries of
B
H
2
+
BH_2^+
B
H
2
+
and
N
H
2
+
NH_2^+
N
H
2
+
, based on valence shell electron pair repulsion (VSEPR) theory is
IIT JAM CY - 2022
IIT JAM CY
Inorganic Chemistry
Chemical bonding and molecular structure
The Maxwell-Boltzmann distribution
f
(
v
x
)
f(v_x)
f
(
v
x
)
of one-dimensional velocities
v
x
v_x
v
x
at temperature T is [Given: A is a normalization constant such that
∫
−
∞
∞
f
(
v
x
)
d
v
x
=
1
\int_{-\infty}^{\infty} f(v_x) dv_x = 1
∫
−
∞
∞
f
(
v
x
)
d
v
x
=
1
, and
k
B
k_B
k
B
is the Boltzmann constant]
IIT JAM CY - 2022
IIT JAM CY
Physical Chemistry
Gaseous State
All possible lattice types are observed in the
IIT JAM CY - 2022
IIT JAM CY
Physical Chemistry
Solid State
The ground state and the maximum number of spin-allowed electronic transitions possible in a
C
o
2
+
Co^{2+}
C
o
2
+
tetrahedral complex, respectively, are
IIT JAM CY - 2022
IIT JAM CY
Inorganic Chemistry
d block elements
The number of signals observed in the
1
H
N
M
R
^1H NMR
1
H
NMR
spectrum of the compound
is _________.
IIT JAM CY - 2022
IIT JAM CY
Physical Chemistry
Spectroscopy
Among of the following
the number of aromatic compounds is _______ .
IIT JAM CY - 2022
IIT JAM CY
Organic Chemistry
Heterocyclic Chemistry
Among the following, the correct statement(s) is/are:
IIT JAM CY - 2022
IIT JAM CY
Organic Chemistry
Organic Chemistry- Some Basic Principles and Techniques
Capillary W contains water and capillary M contains mercury. The contact angles between the capillary wall and the edge of the meniscus at the air-liquid interface in
W
W
W
and
M
M
M
are
θ
W
\theta_W
θ
W
and
θ
M
\theta_M
θ
M
, respectively. The contact angles satisfy the conditions
IIT JAM CY - 2022
IIT JAM CY
Physical Chemistry
Liquid state
The number of CO stretching bands in the infrared spectrum of
F
e
(
C
O
)
5
Fe(CO)_5
F
e
(
CO
)
5
is
IIT JAM CY - 2022
IIT JAM CY
Physical Chemistry
Spectroscopy
Prev
1
2
3
Next