>
Inorganic Chemistry
List of top Inorganic Chemistry Questions
The ground state of [Cr(H
2
O)
6
]
2+
is
GATE CY - 2024
GATE CY
Inorganic Chemistry
Coordination chemistry
The bond length of CO is 113 pm and its dipole moment (𝜇⃗) is 0.1 D. The charge (in units of electronic charge) on carbon in the CO molecule including its sign is (rounded off to three decimal places)
[Given: charge of electron = 1.602×10
−19
C; 1 D=3.336 × 10
−30
Cm]
IIT JAM CY - 2024
IIT JAM CY
Inorganic Chemistry
Chemical bonding and molecular structure
In aqueous solution of K
4
[Fe(CN)
6
], the allowed transition(s) is (are)
GATE CY - 2024
GATE CY
Inorganic Chemistry
Coordination chemistry
The order and the number of classes present in a group with the irreducible representations A
1
, A
2
, B
1
, B
2
, E
1
, and E
2
, are, respectively,
GATE CY - 2024
GATE CY
Inorganic Chemistry
Mass spectrometry
1
H NMR spectrum of a mixture containing CH
3
Br (x mol) and (CH
3
)
3
CBr (y mol) shows two singlets at 2.7 ppm and 1.8 ppm, with the relative ratio of 3:1 (integration value), respectively. The value of x/y is ______.
(rounded off to the nearest integer)
GATE CY - 2024
GATE CY
Inorganic Chemistry
NMR and ESR spectroscopy
Among [Ti(H2O)
6
]
3+
,[NiCl
4
]
2−
,[CrO
4
]
2−
,and [Mn(H
2
O)
6
]
2+
, the complex that exhibits the largest molar absorptivity in the visible region of the electronic absorption spectrum is
IIT JAM CY - 2024
IIT JAM CY
Inorganic Chemistry
d block elements
[Co(NH
3
)
5
(SO
4
)]Br and [Co(NH
3
)
5
Br]SO
4
are examples of
IIT JAM CY - 2024
IIT JAM CY
Inorganic Chemistry
d block elements
For the reaction shown below
the oxidation states of Mn in P and Q, respectively, are
IIT JAM CY - 2024
IIT JAM CY
Inorganic Chemistry
d block elements
The magnetic moment of O
3
molecule is _______ Bohr magneton (B.M.). (rounded off to the nearest integer)
IIT JAM CY - 2024
IIT JAM CY
Inorganic Chemistry
Chemical bonding and molecular structure
The number and nature of d−d transition(s) in the case of Sc
2+
in an octahedral crystal field, respectively, are
[Ignore spin-orbit coupling and Jahn-Teller distortion.]
IIT JAM CY - 2024
IIT JAM CY
Inorganic Chemistry
d block elements
Zn–C bond polarity in the compounds below
follows the order
IIT JAM CY - 2024
IIT JAM CY
Inorganic Chemistry
Chemical bonding and molecular structure
Elements and their processes of extraction/purification are given. The correct pair(s) is/are
IIT JAM CY - 2024
IIT JAM CY
Inorganic Chemistry
Extractions of Metals
The correct statement(s) about the ligand substitution/exchange reaction is/are
IIT JAM CY - 2024
IIT JAM CY
Inorganic Chemistry
d block elements
The d-d transitions in [Mn(H2O)6]
2+
and [Ti(H2O)4]
3+
, respectively, are [Ignore spin-orbit coupling and Jahn-Teller distortion.]
IIT JAM CY - 2024
IIT JAM CY
Inorganic Chemistry
d block elements
The N–O bond order in [NO]
−
is _______
IIT JAM CY - 2024
IIT JAM CY
Inorganic Chemistry
Chemical bonding and molecular structure
The reaction of XeF
2
with HN(SO
2
F)
2
at 273 K in CF
2
Cl
2
solvent yields
GATE CY - 2024
GATE CY
Inorganic Chemistry
Theories of bonding
Among the following, the NMR active nucleus (nuclei) is (are)
GATE CY - 2024
GATE CY
Inorganic Chemistry
NMR and ESR spectroscopy
The heptacity of allyl and Cp and the ligation mode of NO in the thermodynamically stable complexes
[(η
x
-allyl)Ru(CO)
2
(NO)] and [(η
y
-Cp)Ru(CO)2(NO)],
respectively, are
(The heptacity of allyl and Cp are denoted by η
x
and η
y
, respectively.)
GATE CY - 2024
GATE CY
Inorganic Chemistry
Coordination chemistry
Borax on treatment with NaOH and H
2
O
2
forms X. The compound X on reaction with PhCN at 60 °C in methanol-water mixture gives Y as the major product. X and Y, respectively, are
GATE CY - 2024
GATE CY
Inorganic Chemistry
Structure and Bonding of Boranes
The crystal field stabilization energy of [Cr(NH
3
)
6
]
3+
with Δ
0
value of 21600 cm
-1
is y cm
-1
. The value of |y| is_____.
(rounded off to the nearest integer)
GATE CY - 2024
GATE CY
Inorganic Chemistry
Energy level diagrams in various crystal fields
The number of metal-metal bond(s) in the complex [(
5
η-Cp)Mo(CO)
2
]
2
is x and in [(
5
η-Cp)2Fe
2
(CO)
3
] is y. The value of x + y is ____.
(Assume 18 electron rule is followed.)
(Answer in integer)
GATE CY - 2024
GATE CY
Inorganic Chemistry
Metal-carbonyl
Among the following metalloproteins, the pair(s) of non-heme proteins is (are)
GATE CY - 2024
GATE CY
Inorganic Chemistry
Iron
The compound(s) which show(s) the perovskite structure in solid state is (are)
GATE CY - 2024
GATE CY
Inorganic Chemistry
Crystal systems and lattices
The complex(es) with distorted octahedral structure is (are)
GATE CY - 2024
GATE CY
Inorganic Chemistry
Coordination chemistry
The major product in the given reaction sequence is Q. The mass spectrum of Q shows
([M] = molecular ion peak)
GATE CY - 2024
GATE CY
Inorganic Chemistry
Mass spectrometry
Prev
1
2
3
Next