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Inorganic Chemistry
List of top Inorganic Chemistry Questions
The ground state of [Cr(H
2
O)
6
]
2+
is
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Inorganic Chemistry
Coordination chemistry
The major product in the given reaction sequence is Q. The mass spectrum of Q shows
([M] = molecular ion peak)
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Inorganic Chemistry
Mass spectrometry
In aqueous solution of K
4
[Fe(CN)
6
], the allowed transition(s) is (are)
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Inorganic Chemistry
Coordination chemistry
Among [Ti(H2O)
6
]
3+
,[NiCl
4
]
2−
,[CrO
4
]
2−
,and [Mn(H
2
O)
6
]
2+
, the complex that exhibits the largest molar absorptivity in the visible region of the electronic absorption spectrum is
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Inorganic Chemistry
d block elements
For the reaction shown below
the oxidation states of Mn in P and Q, respectively, are
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Inorganic Chemistry
d block elements
The bond length of CO is 113 pm and its dipole moment (𝜇⃗) is 0.1 D. The charge (in units of electronic charge) on carbon in the CO molecule including its sign is (rounded off to three decimal places)
[Given: charge of electron = 1.602×10
−19
C; 1 D=3.336 × 10
−30
Cm]
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Inorganic Chemistry
Chemical bonding and molecular structure
The N–O bond order in [NO]
−
is _______
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Inorganic Chemistry
Chemical bonding and molecular structure
The d-d transitions in [Mn(H2O)6]
2+
and [Ti(H2O)4]
3+
, respectively, are [Ignore spin-orbit coupling and Jahn-Teller distortion.]
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Inorganic Chemistry
d block elements
The magnetic moment of O
3
molecule is _______ Bohr magneton (B.M.). (rounded off to the nearest integer)
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Inorganic Chemistry
Chemical bonding and molecular structure
The correct statement(s) about the ligand substitution/exchange reaction is/are
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Inorganic Chemistry
d block elements
Elements and their processes of extraction/purification are given. The correct pair(s) is/are
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Inorganic Chemistry
Extractions of Metals
Zn–C bond polarity in the compounds below
follows the order
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Inorganic Chemistry
Chemical bonding and molecular structure
The number and nature of d−d transition(s) in the case of Sc
2+
in an octahedral crystal field, respectively, are
[Ignore spin-orbit coupling and Jahn-Teller distortion.]
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Inorganic Chemistry
d block elements
[Co(NH
3
)
5
(SO
4
)]Br and [Co(NH
3
)
5
Br]SO
4
are examples of
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Inorganic Chemistry
d block elements
The complex(es) with distorted octahedral structure is (are)
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Inorganic Chemistry
Coordination chemistry
1
H NMR spectrum of a mixture containing CH
3
Br (x mol) and (CH
3
)
3
CBr (y mol) shows two singlets at 2.7 ppm and 1.8 ppm, with the relative ratio of 3:1 (integration value), respectively. The value of x/y is ______.
(rounded off to the nearest integer)
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Inorganic Chemistry
NMR and ESR spectroscopy
The order and the number of classes present in a group with the irreducible representations A
1
, A
2
, B
1
, B
2
, E
1
, and E
2
, are, respectively,
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Inorganic Chemistry
Mass spectrometry
The reaction of XeF
2
with HN(SO
2
F)
2
at 273 K in CF
2
Cl
2
solvent yields
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Inorganic Chemistry
Theories of bonding
Among the following, the NMR active nucleus (nuclei) is (are)
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Inorganic Chemistry
NMR and ESR spectroscopy
The heptacity of allyl and Cp and the ligation mode of NO in the thermodynamically stable complexes
[(η
x
-allyl)Ru(CO)
2
(NO)] and [(η
y
-Cp)Ru(CO)2(NO)],
respectively, are
(The heptacity of allyl and Cp are denoted by η
x
and η
y
, respectively.)
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Inorganic Chemistry
Coordination chemistry
Borax on treatment with NaOH and H
2
O
2
forms X. The compound X on reaction with PhCN at 60 °C in methanol-water mixture gives Y as the major product. X and Y, respectively, are
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Inorganic Chemistry
Structure and Bonding of Boranes
The number of metal-metal bond(s) in the complex [(
5
η-Cp)Mo(CO)
2
]
2
is x and in [(
5
η-Cp)2Fe
2
(CO)
3
] is y. The value of x + y is ____.
(Assume 18 electron rule is followed.)
(Answer in integer)
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Inorganic Chemistry
Metal-carbonyl
The crystal field stabilization energy of [Cr(NH
3
)
6
]
3+
with Δ
0
value of 21600 cm
-1
is y cm
-1
. The value of |y| is_____.
(rounded off to the nearest integer)
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Inorganic Chemistry
Energy level diagrams in various crystal fields
The compound(s) which show(s) the perovskite structure in solid state is (are)
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Inorganic Chemistry
Crystal systems and lattices
Among the following metalloproteins, the pair(s) of non-heme proteins is (are)
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Inorganic Chemistry
Iron
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