In the separation of $Cu^{2+}$ and $Cd^{2+}$ of Ilnd group in qualitative analysis of cations, tetrammine copper (II) sulphate and tetrammine cadmium (II) sulphate react with KCN to form the corresponding cyano complexes, which one of the following pairs of the complexes and their relative stability enables the separation of $Cu^{2+} $ and $Cd^{2+}$?