Lassaigne’s test is used to detect the presence of nitrogen, sulfur, and halogens in organic compounds. In this test, the compound is fused with sodium to convert these elements into ionic forms (e.g., NaCN for nitrogen).
To give a positive result for nitrogen in Lassaigne’s test, the compound must contain a carbon-nitrogen bond. During fusion with sodium, nitrogen forms cyanide ions (\( \text{CN}^- \)), which can be detected in subsequent steps.
Phenyl hydrazine (\( \text{C}_6\text{H}_5\text{NHNH}_2 \)): Contains a carbon-nitrogen bond and will give a positive result for Lassaigne’s test.
Glycine (\( \text{NH}_2\text{CH}_2\text{COOH} \)): Contains a carbon-nitrogen bond in the amino acid structure and will give a positive result for Lassaigne’s test.
Urea (\( \text{NH}_2\text{CONH}_2 \)): Contains a carbon-nitrogen bond in the amide linkage and will give a positive result for Lassaigne’s test.
Hydrazine (\( \text{NH}_2\text{NH}_2 \)): Does not contain any carbon atoms; therefore, it cannot form \( \text{NaCN} \) and does not give a positive Lassaigne’s test for nitrogen.
Hydrazine does not contain a carbon-nitrogen bond and hence does not give Lassaigne’s test.
The correct answer is Option (4).
The monomer (X) involved in the synthesis of Nylon 6,6 gives positive carbylamine test. If 10 moles of X are analyzed using Dumas method, the amount (in grams) of nitrogen gas evolved is ____. Use: Atomic mass of N (in amu) = 14
The correct match of the group reagents in List-I for precipitating the metal ion given in List-II from solutions is:
List-I | List-II |
---|---|
(P) Passing H2S in the presence of NH4OH | (1) Cu2+ |
(Q) (NH4)2CO3 in the presence of NH4OH | (2) Al3+ |
(R) NH4OH in the presence of NH4Cl | (3) Mn2+ |
(S) Passing H2S in the presence of dilute HCl | (4) Ba2+ (5) Mg2+ |
Match List I with List II:
Choose the correct answer from the options given below:
Among the following cations, the number of cations which will give characteristic precipitate in their identification tests with
\(K_4\)[Fe(CN)\(_6\)] is : \[ {Cu}^{2+}, \, {Fe}^{3+}, \, {Ba}^{2+}, \, {Ca}^{2+}, \, {NH}_4^+, \, {Mg}^{2+}, \, {Zn}^{2+} \]