To solve the problem, we need to identify the substance used as a flux in the smelting of haematite (Fe2O3).
1. Understanding the Role of Flux:
A flux is a substance added during smelting to combine with impurities (gangue) to form a slag. This slag is easily removable.
2. Nature of Gangue in Haematite:
The main impurity present during the smelting of haematite is **silica (SiO2)**, which is acidic in nature.
3. Required Flux:
To remove acidic impurities like SiO2, we use a basic flux. The most commonly used basic flux is **calcium carbonate (CaCO3)**, which decomposes on heating to form CaO. CaO then reacts with SiO2 to form calcium silicate (CaSiO3), which is the slag.
Reaction:
\[
\text{CaCO}_3 \xrightarrow{\Delta} \text{CaO} + \text{CO}_2
\]
\[
\text{CaO} + \text{SiO}_2 \rightarrow \text{CaSiO}_3 \ (\text{slag})
\]
Final Answer:
The correct answer is option (C): CaCO3.