The photoelectric effect is described by Einstein's photoelectric equation:
\[ K_{\text{max}} = h \nu - \phi \]where:
The stopping potential \( V \) is related to the maximum kinetic energy by:
\[ K_{\text{max}} = eV \]Thus, we can write the equation for stopping potential as:
\[ eV = h \nu - \phi \]We are given that the stopping potential is \( V \) when the wavelength of the incident light is \( \lambda \). Therefore, the energy equation for this situation is:
\[ eV = h \frac{c}{\lambda} - \phi \]where \( c \) is the speed of light.
Now, when the wavelength of the light is \( 2\lambda \), the stopping potential is \( \frac{V}{4} \). The energy equation for this situation becomes:
\[ e \frac{V}{4} = h \frac{c}{2\lambda} - \phi \] Step 1: Subtract the two equationsNow, we subtract the second equation from the first to eliminate the work function \( \phi \):
\[ eV - e \frac{V}{4} = h \left( \frac{c}{\lambda} - \frac{c}{2\lambda} \right) \]Simplifying:
\[ \frac{3eV}{4} = h \left( \frac{c}{2\lambda} \right) \] \[ \frac{3eV}{4} = \frac{hc}{2\lambda} \] Step 2: Solve for \( V \)Now, we can solve for the wavelength \( \lambda \):
\[ V = \frac{2\lambda e}{hc} \times 3 \]Thus, the threshold wavelength is \( 3\lambda \).
Thus, the correct answer is Option (3), \( 3\lambda \).
Which of the following are ambident nucleophiles?
[A.] CN$^{\,-}$
[B.] CH$_{3}$COO$^{\,-}$
[C.] NO$_{2}^{\,-}$
[D.] CH$_{3}$O$^{\,-}$
[E.] NH$_{3}$
Identify the anomers from the following.

The standard Gibbs free energy change \( \Delta G^\circ \) of a cell reaction is \(-301 { kJ/mol}\). What is \( E^\circ \) in volts?
(Given: \( F = 96500 { C/mol}\), \( n = 2 \))