Step 1: Understand the Van't Hoff factor.
The Van't Hoff factor \( i \) represents the number of particles into which a solute dissociates in solution.
For solutes that dissociate in water, such as salts, \( i \) is greater than 1 because the solute dissociates into multiple ions.
Step 2: Identify the correct option.
For dissociating solutes (like NaCl), \( i \) will be greater than 1, as each formula unit dissociates into two or more ions.