Step 1: Identify possible outcomes.
When two dice are tossed, the total number of possible outcomes is $6 \times 6 = 36$. Step 2: Identify prime sums.
Possible prime sums are $2, 3, 5, 7, 11$. Step 3: Count favorable outcomes.
Sum = 2 $\rightarrow$ 1 outcome
Sum = 3 $\rightarrow$ 2 outcomes
Sum = 5 $\rightarrow$ 4 outcomes
Sum = 7 $\rightarrow$ 6 outcomes
Sum = 11 $\rightarrow$ 2 outcomes
Total favorable outcomes = $1 + 2 + 4 + 6 + 2 = 15$. Step 4: Calculate probability.
\[
P = \frac{15}{36} = \frac{5}{12}
\]