Question:

The ratio of vapour densities of two gases at the same temperature is \( \frac{4}{25} \), then the ratio of r.m.s. velocities will be:

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The r.m.s. velocity of a gas is inversely proportional to the square root of its molecular mass. Vapour density is directly proportional to the molecular mass.
Updated On: Mar 17, 2025
  • \( \frac{25}{4} \)
  • \( \frac{2}{5} \)
  • \( \frac{5}{2} \)
  • \( \frac{4}{25} \)
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The Correct Option is C

Solution and Explanation

Step 1: Given Vapour Density Ratio

We are given the ratio of the vapour densities as: \[ \frac{\rho_1}{\rho_2} = \frac{4}{25} \]

Step 2: Relate Vapour Density Ratio to r.m.s. Velocity Ratio

We know that the ratio of r.m.s. velocities \( v_1 \) and \( v_2 \) is related to the ratio of vapour densities by the formula: \[ \frac{v_1}{v_2} = \sqrt{\frac{\rho_2}{\rho_1}} \]

Step 3: Calculate the Ratio of r.m.s. Velocities

Substituting the given vapour density ratio: \[ \frac{v_1}{v_2} = \sqrt{\frac{25}{4}} = \frac{5}{2} \]

Final Answer: \[ \frac{v_1}{v_2} = \frac{5}{2} \]
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