For \(PV^{3/2} = \text{constant}\), we know that:
\[ W = \int P \, dV \]
Since \(P = \frac{K}{V^{3/2}}\):
\[ W = \int_{V_1}^{V_2} \frac{K}{V^{3/2}} \, dV \]
Integrating, we get:
\[ W = \left[ -\frac{2K}{V^{1/2}} \right]_{V_1}^{V_2} = 2(P_1V_1 - P_2V_2) \]
- If the work done by the gas is asked:
\[ W = 2(P_1V_1 - P_2V_2) \quad \text{(Option 1)} \]
- If the work done on the gas (by external) is asked:
\[ W = 2(P_2V_2 - P_1V_1) \quad \text{(Option 2)} \]
The excess molar Gibbs free energy of a solution of element A and B at 1000 K is given by \( G^{XS} = -3000 X_A X_B \) J mol\(^{-1}\), where \( X_A \) and \( X_B \) are mole fractions of A and B, respectively. The activity of B in a solution of A and B containing 40 mol% of B at 1000 K is ......... (rounded off to two decimal places). Given: Ideal gas constant \( R = 8.314 \, {J mol}^{-1} {K}^{-1} \)
Consider the following cell reaction: \[ {Mg} + {Cd}^{2+} \rightleftharpoons {Mg}^{2+} + {Cd} \] The standard Gibbs free energy change for the reaction is _________ kJ (rounded off to an integer). Given: Standard oxidation potentials for the reactions with respect to the standard hydrogen electrode are:
Mg \( \rightleftharpoons \) Mg\(^{2+}\) + 2e\(^-\) \( E^\circ = 2.37 \, {V} \) Cd \( \rightleftharpoons \) Cd\(^{2+}\) + 2e\(^-\) \( E^\circ = 0.403 \, {V} \) Faraday’s constant = 96500 C mol\(^{-1}\)
Match List-I with List-II: