The internal energy of air in $ 4 \, \text{m} \times 4 \, \text{m} \times 3 \, \text{m} $ sized room at 1 atmospheric pressure will be $ \times 10^6 \, \text{J} $. (Consider air as a diatomic molecule)
We are given a room of size \(4\,\text{m} \times 4\,\text{m} \times 3\,\text{m}\), filled with air at 1 atm pressure. We must find its total internal energy assuming air behaves as a diatomic ideal gas.
For an ideal gas, internal energy is given by:
\[ U = nC_vT \]where \(n\) is the number of moles and \(C_v\) is the molar specific heat at constant volume.
For a diatomic gas (air), \(C_v = \frac{5}{2}R.\)
Step 1: Calculate the volume of the room.
\[ V = 4\times4\times3 = 48\,\text{m}^3. \]Step 2: Using the ideal gas equation \( PV = nRT \), we can express the number of moles as:
\[ n = \frac{PV}{RT}. \]Step 3: Internal energy per mole of gas is \( U = nC_vT = n \frac{5}{2}RT \).
Substitute \( n = \frac{PV}{RT} \):
\[ U = \frac{PV}{RT} \cdot \frac{5}{2}RT = \frac{5}{2}PV. \]Step 4: Substitute the values:
\[ P = 1\,\text{atm} = 1.013\times10^5\,\text{Pa}, \quad V = 48\,\text{m}^3. \] \[ U = \frac{5}{2}\times(1.013\times10^5)\times48. \] \[ U = 2.5 \times 1.013\times10^5 \times 48 = 1.2156\times10^7\,\text{J}. \]Answer: \( \boxed{12.2\times10^6\ \text{J}} \)
A hot plate is placed in contact with a cold plate of a different thermal conductivity as shown in the figure. The initial temperature (at time $t = 0$) of the hot plate and cold plate are $T_h$ and $T_c$, respectively. Assume perfect contact between the plates. Which one of the following is an appropriate boundary condition at the surface $S$ for solving the unsteady state, one-dimensional heat conduction equations for the hot plate and cold plate for $t>0$?

The following data is given for a ternary \(ABC\) gas mixture at 12 MPa and 308 K:

\(y_i\): mole fraction of component \(i\) in the gas mixture
\(\hat{\phi}_i\): fugacity coefficient of component \(i\) in the gas mixture at 12 MPa and 308 K
The fugacity of the gas mixture is _________ MPa (rounded off to 3 decimal places).
