The electron configuration for the element with atomic number Z = 17 (Chlorine) is:
\[
1s^2 2s^2 2p^6 3s^2 3p^5
\]
The unpaired electron in the 3p orbital has the following quantum numbers:
- Principal quantum number \( n = 3 \) (since it is in the third shell)
- Azimuthal quantum number \( l = 1 \) (since it is in a p orbital)
- Magnetic quantum number \( m_l = 1 \) (can take values between \(-l\) and \(+l\))
- Spin quantum number \( m_s = \pm \frac{1}{2} \) (the electron has a half-spin)
Thus, the correct set of quantum numbers is (a).