Question:

Statement-1: Methyl orange is a weak acid 
Statement-2: Benzenoid form of methyl orange is deeply coloured than quinonoid form
Check out which of the above statement is true?

Show Hint

Acid-base indicators like methyl orange change color due to structural transformations between their benzenoid and quinonoid forms. The quinonoid form is generally more deeply colored

Updated On: Mar 21, 2025
  • Statement-1 is correct and Statement-2 is wrong
  • Both the Statements-1 and Statement-2 are correct
  • Statement-1 is wrong and Statement-2 is correct
  • None of them
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The Correct Option is A

Solution and Explanation

Analysis of Statements on Methyl Orange: 

Statement I:

Methyl orange is not a weak acid; it is an acid-base indicator that exists in different structural forms depending on the pH of the solution:

  • In acidic solutions, methyl orange exists in its protonated form.
  • In basic solutions, it undergoes deprotonation to form a conjugate base.

Conclusion: Since methyl orange is not classified as a weak acid, Statement I is incorrect.

Statement II:

The color intensity of methyl orange depends on its structural form:

  • The quinonoid form of methyl orange is more intensely or deeply colored and is responsible for the orange/red coloration in acidic media.
  • The benzenoid form is less intensely colored and contributes to the yellow coloration in basic media.

Since the statement incorrectly claims that the benzenoid form is more intensely colored, Statement II is also incorrect.

Final Conclusion:

Since both Statement I and Statement II are incorrect, the correct answer is option (1).

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Concepts Used:

Amines

Amine is a type of compound which is derived from ammonia (NH3). According to Organic chemistry, they are basically classified as the functional groups of the organic nitrogen compounds that contain nitrogen atoms with a lone pair.

Amine - Types

Primary Amines:

It is formed when one hydrogen atom in ammonia is substituted by an alkyl or aromatic group. Amino acids and methyl amine are the best examples that why aromatic amines include aniline.

Secondary Amines:

Amines that have two organic substitutes either alkyl or aryl ones or both and are bound to the nitrogen together with one hydrogen are termed as secondary amines. For Example, Dimethylamine.

Tertiary Amines:

Tertiary Amines are the amines where the nitrogen consists of three organic substitutes. For example, Trimethylamine and EDTA.