Understand each linkage and structure in the context of DNA.
A. 3'-5' phosphodiester linkage connects one nucleotide to another via phosphate groups. So, it matches with II: Nucleotide + Nucleotide.
B. N-Glycosidic Linkage connects the nitrogenous base to the sugar. Hence, it matches with I: Nitrogen base + Sugar.
C. 5' end of the polynucleotide refers to the end with a free phosphate group. So, it matches with IV: Free phosphate moiety.
D. Backbone of DNA is formed by repeated sugar-phosphate groups. So, it matches with III: Sugar + Phosphate.
Step 2: Match accordingly.
A → II
B → I
C → IV
D → III