Question:
Match List I with List IIList I (Complex) List II (Hybridization) A. Ni(CO)4 I. sp3 B. [Cu(NH3)4]2+ II. dsp2 C. [Fe(NH3)6]2+ III. sp3d2 D. [Fe(H2O)6]2+ IV. d2sp3
Choose the correct answer from the options given below:
Match List I with List II
Choose the correct answer from the options given below:
| List I (Complex) | List II (Hybridization) | ||
| A. | Ni(CO)4 | I. | sp3 |
| B. | [Cu(NH3)4]2+ | II. | dsp2 |
| C. | [Fe(NH3)6]2+ | III. | sp3d2 |
| D. | [Fe(H2O)6]2+ | IV. | d2sp3 |
Updated On: Jan 4, 2025
- A-I, B-II, C-III, D-IV
- A-II, B-I, C-III, D-IV
- A-I, B-II, C-IV, D-III
- A-II, B-I, C-IV, D-III
Hide Solution
Verified By Collegedunia
The Correct Option is C
Solution and Explanation
The correct answer is (C) : A-I, B-II, C-IV, D-III
For [Fe(NH3)6]+2,Δ0<P, hence the pairing of electrons does not occur in t2g.
Therefore complex is outer orbital and its hybridisation is sp3d2.
Was this answer helpful?
2
2
Top Questions on coordination compounds
- Which of the following species exhibits both LMCT and paramagnetism?
- WBJEE - 2024
- Chemistry
- coordination compounds
- Identify correct statements from below:
A. The chromate ion is square planar.
B. Dichromates are generally prepared from chromates.
C. The green manganate ion is diamagnetic.
D. Dark green coloured \(K_2MnO_4\) disproportionates in a neutral or acidic medium to give permanganate.
E. With increasing oxidation number of transition metal, ionic character of the oxides decreases.
Choose the correct answer from the options given below:- JEE Main - 2024
- Chemistry
- coordination compounds
Match the following:
Ions Properties I. Zn2+ i. d8 configuration II. Cu2+ ii. Colourless III. Ni2+ iii. µ = 1.73 BM Codes:
- KCET - 2024
- Chemistry
- coordination compounds
- Which of the following statements are true about [CoF6]3− ion?
I) The complex has octahedral geometry.
II) Coordination number of Co is 3 and oxidation state is +6.
(III) The complex is sp3d2 hybridised.
(IV) It is a high spin complex.- KCET - 2024
- Chemistry
- coordination compounds
- On treating 100 mL of 0.1 M aqueous solution of the complex CrCl₃.6H₂O with excess of AgNO₃, 2.86 g of AgCl was obtained. The complex is:
- KCET - 2024
- Chemistry
- coordination compounds
View More Questions
Questions Asked in JEE Main exam
- A rectangular loop of length 2.5 m and width 2 m is placed at 60° to a magnetic field of 4 T. The loop is removed from the field in 10 sec. The average emf induced in the loop during this time is:
- JEE Main - 2024
- Electromagnetic induction
- Two coils have mutual inductance 0.002 H. The current changes in the first coil according to the relation \( i = i_0 \sin \omega t \), where \( i_0 = 5 \, \text{A} \) and \( \omega = 50\pi \, \text{rad/s} \). The maximum value of emf in the second coil is \( \frac{\pi}{\alpha} \). The value of \( \alpha \) is ______.
- JEE Main - 2024
- Electromagnetic induction
- The 20th term from the end of the progression \[ 20, 19, \frac{1}{4}, \frac{1}{2}, \frac{3}{4}, \ldots, -129 \frac{1}{4} \] is:
- JEE Main - 2024
- Arithmetic Progression
- We have three aqueous solutions of NaCl labelled as ‘A’, ‘B’ and ‘C’ with concentration 0.1 M, 0.01M & 0.001 M, respectively. The value of vant’ Haft factor (i) for these solutions will be in the order.
- JEE Main - 2024
- Colligative Properties
- $\Delta_{vap}H^\circ$ for water is $+40.49 \, \text{kJ mol}^{-1}$ at 1 bar and $100^\circ\text{C}$. Change in internal energy for this vaporisation under same condition is .............. kJ mol$^{-1}$. (Integer answer)
(Given R = 8.3 J K$^{-1}$ mol$^{-1}$)- JEE Main - 2024
- Enthalpy change
View More Questions
Concepts Used:
Coordination Compounds
A coordination compound holds a central metal atom or ion surrounded by various oppositely charged ions or neutral molecules. These molecules or ions are re-bonded to the metal atom or ion by a coordinate bond.
Coordination entity:
A coordination entity composes of a central metal atom or ion bonded to a fixed number of ions or molecules.
Ligands:
A molecule, ion, or group which is bonded to the metal atom or ion in a complex or coordination compound by a coordinate bond is commonly called a ligand. It may be either neutral, positively, or negatively charged.