Question:

Match List I with List II.
 List I (Anion) List II (gas evolved on reaction with dil \(H_2SO_4\))
A.\(CO_3^{ 2−}\)I.Colourless gas which turns lead acetate paper black.
B.\(S^{2–}\)II.Colourless gas which turns acidified potassium dichromate solution green
C.\(SO_3^{ 2−}\)III.Brown fumes which turns acidified KI solution containing starch blue.
D.\(NO_2^{−}\)IV.Colourless gas evolved with brisk effervescence, which turns lime water milky.
Choose the correct answer from the options given below:

Updated On: Jul 6, 2024
  • A-III, B-I, C-II, D-IV
  • A-II, B-I, C-IV, D-III
  • A-IV, B-I, C-III, D-II
  • A-IV, B-I, C-II, D-III
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The Correct Option is D

Solution and Explanation

\(CO_3^{ 2−}\): On action of diluted sulphuric acid, \(CO_2\) gas is released which turns lime water milky.

\(S ^{2-}:\) On action of diluted sulphuric acid, \(H_2S\) gas is released which turns lead acetate paper black.

\(SO_3^{ 2−}\): On action of diluted \( H_2SO_4, SO_2\) gas is evolved which turns acidified potassium dichromate solution green.

\(NO^{2−}\): On action of dil \(H_2SO_4, NO_2\) gas is evolved which turns Kl solution contain starch blue.

\(Hence,\) the correct option is (D): \(A-IV, B-I, C-II, D-III\)

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Concepts Used:

Gas Laws

The gas laws were developed at the end of the 18th century, when scientists began to realize that relationships between pressure, volume and temperature of a sample of gas could be obtained which would hold to approximation for all gases.

The five gas laws are:

  • Boyle’s Law, which provides a relationship between the pressure and the volume of a gas.
  • Charles’s Law, which provides a relationship between the volume occupied by a gas and the absolute temperature.
  • Gay-Lussac’s Law, which provides a relationship between the pressure exerted by a gas on the walls of its container and the absolute temperature associated with the gas.
  • Avogadro’s Law, which provides a relationship between the volume occupied by a gas and the amount of gaseous substance.
  • The Combined Gas Law (or the Ideal Gas Law), which can be obtained by combining the four laws listed above.