Question:

In Wilkinson?s catalyst, the hybridization of central metal ion and its shape are respectively :

Updated On: Aug 22, 2024
  • $sp^3d$, trigonal bipyramidal
  • $sp^3$, tetrahedral
  • $dsp^2$, square planar
  • $d^2sp^3$, octahedral
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The Correct Option is C

Solution and Explanation

The formula of Wilkinson's catalyst is $RhCl \left( PPh _{3}\right)_{3} .$ It has square planar geometry with $d s p^{2}$ hybridisation.
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Concepts Used:

Coordination Compounds

A coordination compound holds a central metal atom or ion surrounded by various oppositely charged ions or neutral molecules. These molecules or ions are re-bonded to the metal atom or ion by a coordinate bond.

Coordination entity:

A coordination entity composes of a central metal atom or ion bonded to a fixed number of ions or molecules.

Ligands:

A molecule, ion, or group which is bonded to the metal atom or ion in a complex or coordination compound by a coordinate bond is commonly called a ligand. It may be either neutral, positively, or negatively charged.