Question:

In which of the following is the oxidation state of oxygen \(+2\)?

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Oxygen usually has \(-2\), but in peroxides it’s \(-1\), in superoxides \(-\tfrac{1}{2}\), and in oxygen difluoride it’s \(+2\).
  • F$_2$O
  • Cl$_2$O
  • Na$_2$O$_2$
  • Na$_2$O
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The Correct Option is A

Solution and Explanation

Step 1: Assign oxidation states.
In \( \mathrm{F_2O} \) (oxygen difluoride), fluorine is more electronegative and has \(-1\) each. Let O be \(x\):
\( x + 2(-1) = 0 \Rightarrow x = +2 \).
Step 2: Eliminate others.
Cl$_2$O: O is \(-2\) (Cl is \(+1\)).
Na$_2$O$_2$: Peroxide, O is \(-1\).
Na$_2$O: Oxide, O is \(-2\).
Step 3: Conclusion.
Only F$_2$O has oxygen in the \(+2\) state.
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