Question:

In Dumas method for the estimation of $N _2$, the sample is heated with copper oxide and the gas evolved is passed over :

Show Hint

Dumas' method is commonly used for the estimation of nitrogen in organic compounds by releasing nitrogen gas through heating with copper oxide.
Updated On: Mar 20, 2025
  • Copper gauze
  • $Pd$
  • $Ni$
  • Copper oxide
Hide Solution
collegedunia
Verified By Collegedunia

The Correct Option is A

Approach Solution - 1

Duma's method.
The nitrogen containing organic compound, when heated with in a atmosphere of , yields free in addition to and .


Traces of nitrogen oxides formed, if any, are reduced to nitrogen by passing the gaseous mixture over heated copper gauze.
So, the correct option is (A) : Copper gauze
Was this answer helpful?
0
0
Hide Solution
collegedunia
Verified By Collegedunia

Approach Solution -2

In Dumas' method, the nitrogen-containing organic compound is heated with copper oxide in an atmosphere of CO\(_2\). 
The resulting reaction produces nitrogen gas in addition to CO\(_2\) and H\(_2\)O:

\[ C_xH_yN_z + \left( 2x + \frac{y}{2} \right) \text{CuO} \rightarrow x \text{CO}_2 + \frac{y}{2} \text{H}_2\text{O} + \frac{z}{2} \text{N}_2 + \left( 2x + \frac{y}{2} \right) \text{Cu} \]

Afterward, any nitrogen oxides formed are reduced to nitrogen gas by passing the gaseous mixture over heated copper gauze.

Was this answer helpful?
0
0

Concepts Used:

Organic Chemistry - Some Basic Principles and Techniques

Organic Chemistry is a subset of chemistry dealing with compounds of carbon. Therefore, we can say that Organic chemistry is the chemistry of carbon compounds and is 200-225 years old. Carbon forms bond with itself to form long chains of hydrocarbons, e.g.CH4, methane and CH3-CH3 ethane. Carbon has the ability to form carbon-carbon bonds quite elaborately. Polymers like polyethylene is a linear chain where hundreds of CH2 are linked together. 

Read Also: Organic Compounds

Importance of Organic Chemistry:

Organic chemistry is applicable in a variety of areas including-

  • Medicines: Example- Aspirin which is a headache medicine and Ibuprofen is a painkiller, both are organic compounds. Other examples include paracetamol.
  • Food: Example- Starch which is a carbohydrate is an organic compound and a constituent of rice and other grains. It is the source of energy.
  • Clothing: Example- Nylon, Polyester and Cotton are forms of organic compounds.
  • Fuels: Examples- Gasoline, Petrol and Diesel are organic compounds used in the automobile industry at large.