Step 1: Understanding the Principle of a Meter Bridge A meter bridge works on the principle of the Wheatstone bridge: \[ \frac{R}{S} = \frac{l_1}{100 - l_1} \] where:
- \( R \) is the unknown resistance in the left gap.
- \( S \) is the resistance in the right gap.
- \( l_1 \) is the initial balance length (null point), given as \(25\) cm.
Step 2: Applying the Given Condition If the resistance \( R \) in the left gap is increased by 100%, the new resistance becomes \( 2R \). The new balance length \( l_2 \) is found using: \[ \frac{2R}{S} = \frac{l_2}{100 - l_2} \] Dividing both equations: \[ \frac{l_2}{100 - l_2} \div \frac{l_1}{100 - l_1} = \frac{2R}{S} \div \frac{R}{S} \] \[ \frac{l_2}{100 - l_2} \times \frac{100 - l_1}{l_1} = 2 \] Substituting \( l_1 = 25 \): \[ \frac{l_2}{100 - l_2} \times \frac{100 - 25}{25} = 2 \] \[ \frac{l_2}{100 - l_2} \times \frac{75}{25} = 2 \] \[ \frac{l_2}{100 - l_2} \times 3 = 2 \] \[ \frac{l_2}{100 - l_2} = \frac{2}{3} \] Solving for \( l_2 \): \[ 3 l_2 = 2(100 - l_2) \] \[ 3 l_2 + 2 l_2 = 200 \] \[ 5 l_2 = 200 \] \[ l_2 = 40 \text{ cm} \]
Step 3: Calculating Percentage Increase \[ \frac{40 - 25}{25} \times 100 = \frac{15}{25} \times 100 = 60\% \] Thus, the correct answer is \( \mathbf{(3)} \ 60\% \).
Observe the following data given in the table. (\(K_H\) = Henry's law constant)
| Gas | CO₂ | Ar | HCHO | CH₄ |
|---|---|---|---|---|
| \(K_H\) (k bar at 298 K) | 1.67 | 40.3 | \(1.83 \times 10^{-5}\) | 0.413 |
The correct order of their solubility in water is
For a first order decomposition of a certain reaction, rate constant is given by the equation
\(\log k(s⁻¹) = 7.14 - \frac{1 \times 10^4 K}{T}\). The activation energy of the reaction (in kJ mol⁻¹) is (\(R = 8.3 J K⁻¹ mol⁻¹\))
Note: The provided value for R is 8.3. We will use the more precise value R=8.314 J K⁻¹ mol⁻¹ for accuracy, as is standard.