The pH value of pure water is 7. This is because, in pure water, the concentration of hydrogen ions (\(H^+\)) and hydroxide ions (\(OH^-\)) are equal, both being \(10^{-7}\) mol/L at 25°C. The pH is calculated as:
\[
\text{pH} = -\log [H^+]
\]
Since \([H^+] = [OH^-] = 10^{-7}\) mol/L for pure water, we get:
\[
\text{pH} = -\log (10^{-7}) = 7
\]
Thus, the pH value of pure water is 7, which is considered neutral.