Here, point \( A \) is the intersection of line \( AB \) and \( AC \). So, the equation of the line passing through \( A \) is given by:
\[
(x + 2y - 1) + \lambda (2x + 3y - 1) = 0
\]
This line passes through the orthocenter \( (0,0) \), hence substituting \( (0,0) \):
\[
-1 + \lambda (-1) = 0
\]
\[
-1 - \lambda = 0
\]
\[
\lambda = -1
\]
Substituting \( \lambda = -1 \) in the equation above, we get:
\[
x + y = 0
\]
Thus, the equation of \( AD \) is:
\[
x + y = 0
\]
Since \( AD \perp BC \), therefore:
\[
\frac{-1 - x}{a} = \frac{d}{b} = -1
\]
which simplifies to:
\[
a + b = 0
\]
Similarly, by applying the condition that \( BE \) is perpendicular to \( CA \), we obtain:
\[
a + 2b = 8
\]
Now, solving the system of equations (3) and (4):
\[
a + b = 0
\]
\[
a + 2b = 8
\]
Subtracting Eq. (3) from Eq. (4):
\[
(a + 2b) - (a + b) = 8 - 0
\]
\[
b = 8
\]
Substituting \( b = 8 \) in Eq. (3):
\[
a + 8 = 0
\]
\[
a = -8
\]
Thus, the values are:
\[
a = -8, \quad b = 8
\]