Given below are two statements:
Statement I : According to the Ellingham diagram, any metal oxide with higher ΔG° is more stable than the one with lower ΔG°.
Statement II :The metal involved in the formation of oxide placed lower in the Ellingham diagram can reduce the oxide of a metal placed higher in the diagram.
In the light of the above statements, choose the most appropriate answer from the options given below
Statement I : According to the Ellingham diagram, any metal oxide with higher ΔG° is more stable than the one with lower ΔG°.
Statement II :The metal involved in the formation of oxide placed lower in the Ellingham diagram can reduce the oxide of a metal placed higher in the diagram.
In the light of the above statements, choose the most appropriate answer from the options given below
- Both Statement I and Statement II are correct.
- Both Statement I and Statement II are incorrect.
- Statement I is correct but Statement II is incorrect.
- Statement I is incorrect but Statement II is correct.
The Correct Option is D
Solution and Explanation
Ellingham diagram is plot of vs T.
The criterion for the feasibility of a thermal reduction is that at a given temperature Gibbs energy change of a reaction must be negative. The change in Gibbs energy,ΔG for any process at any specified temperature, is given by the equation
where ΔH = enthalpy change and = entropy change
According to the ellingham diagram, any metal oxide with higher ΔG° has a tendency of getting reduced by the metal whose metal oxide has lower value of ΔG°.
Therefore, Statement I is incorrect but Statement II is correct.
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Concepts Used:
Occurrence of metals
The existence of metals often plays an important role in our survival, even if we are unaware of them. Our reliance on metals has been strong since the old industrial era. From buildings to jewelry, we utilize them for everything. But where do we acquire these metals from and how are they made? Let's read the occurrence of metal in more detail.
Metals are found in the earth's crust, and it seems to be a good place to extract them through various processes such as metallurgy. The process of extracting metals from ores is called metallurgy. Mining is the most common method of extracting metals from the earth.
In nature, metals are mostly found in mixed conditions. However, they can also be found in a free state. In its natural state, a native metal is one that can be found in its pure form or as part of an alloy. Most metals are exposed to natural processes such as oxidation and corrosion. As a result, only non-reactive metals such as gold, silver, platinum, and others are discovered in their native or open-free condition. Most metals are obtained as compounds, which must be filtered to remove contaminants before being employed in numerous applications.