Given below are two statements:
Statement I: A homoleptic octahedral complex, formed using monodentate ligands, will not show stereoisomerism
Statement II: cis- and trans-platin are heteroleptic complexes of Pd.
In the light of the above statements, choose the correct answer from the options given below
Given below are two statements:
Statement I: A homoleptic octahedral complex, formed using monodentate ligands, will not show stereoisomerism
Statement II: cis- and trans-platin are heteroleptic complexes of Pd.
In the light of the above statements, choose the correct answer from the options given below
Show Hint
- Both Statement I and Statement II are false
- Statement I is true but Statement II is false
- Statement I is false but Statement II is true
- Both Statement I and Statement II are true
The Correct Option is B
Solution and Explanation
- A homoleptic octahedral complex with monodentate ligands (e.g., \([Co(NH_3)_6]^{3+})\) has identical ligands in all positions - No geometrical or optical isomers possible as all positions are equivalent - Therefore, Statement I is true
Analysis of Statement II:
- cis-platin and trans-platin are actually Pt(II) complexes, not Pd - Both are homoleptic complexes (contain same ligands: \([PtCl_2(NH_3)_2])\) - The difference is in ligand arrangement (cis/trans), not heteroleptic nature - Therefore, Statement II is false
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