Given below are two statements. One is labelled as Assertion (A) and the other is labelled as Reason (R):
Assertion (A): In an insulated container, a gas is adiabatically shrunk to half of its initial volume. The temperature of the gas decreases.
Reason (R): Free expansion of an ideal gas is an irreversible and an adiabatic process. \text{In the light of the above statements, choose the correct answer from the options given below:}
- Assertion (A) is true: When a gas is adiabatically compressed to half its initial volume, the temperature decreases. This is a result of the first law of thermodynamics and the fact that no heat is exchanged in an adiabatic process.
- Reason (R) is also true: Free expansion of an ideal gas is an irreversible and adiabatic process.
However, it is not the correct explanation of Assertion (A) because free expansion does not involve compression or a change in volume as described in Assertion (A). Free expansion involves no work and no change in internal energy.
Final Answer: Both (A) and (R) are true but (R) is NOT the correct explanation of (A).
For the thermal decomposition of \( N_2O_5(g) \) at constant volume, the following table can be formed, for the reaction mentioned below: \[ 2 N_2O_5(g) \rightarrow 2 N_2O_4(g) + O_2(g) \] Given: Rate constant for the reaction is \( 4.606 \times 10^{-2} \text{ s}^{-1} \).
Let \( T_r \) be the \( r^{\text{th}} \) term of an A.P. If for some \( m \), \( T_m = \dfrac{1}{25} \), \( T_{25} = \dfrac{1}{20} \), and \( \displaystyle\sum_{r=1}^{25} T_r = 13 \), then \( 5m \displaystyle\sum_{r=m}^{2m} T_r \) is equal to: