Question:

Given below are two statements: One is labelled as Assertion A and the other is labelled as Reason R.  
Assertion A: Butan -1- ol has higher boiling point than ethoxyethane.  
Reason R: Extensive hydrogen bonding leads to stronger association of molecules.  
In the light of the above statements, choose the correct answer from the options given below: 

Updated On: Mar 20, 2025
  • Both A and R are true and R is the correct explanation of A 
  • A is true but R is false 
  • Both A and R are true but R is not the correct explanation of A 
  • A is false but R is true
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The Correct Option is A

Solution and Explanation

Butan-1-ol contains an -OH group, allowing it to form hydrogen bonds, which increase intermolecular forces and raise the boiling point.

Ethoxyethane (ether) cannot form hydrogen bonds due to the lack of an -OH group, resulting in weaker intermolecular forces and a lower boiling point.

Hydrogen bonding is the primary reason for the stronger association of molecules in butan-1-ol compared to ethoxyethane.

Thus, both A and R are true, and R is the correct explanation of A.

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