Question:

Given below are two statements: One is labelled as Assertion A and the other is labelled as Reason $R$
Assertion A: Amongst $He, Ne, Ar$ and $Kr$; $1 g$ of activated charcoal adsorbs more of $Kr$
Reason R: The critical volume $V_c\left( cm ^3 mol ^{-1}\right)$ and critical pressure $P_e$ (atm) is highest for Krypton but the compressibility factor at critical point $Z_c$ is lowest for Krypton 
In the light of the above statements, choose the correct answer from the options given below

Updated On: Aug 13, 2024
  • Both $A$ and $R$ are true but $R$ is NOT the correct explanation of $A$
  • Both $A$ and $R$ are true and $R$ is the correct explanation of $A$
  • A is false but $R$ is true
  • $A$ is true but $R$ is false
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The Correct Option is D

Solution and Explanation

The correct answer is option (D) : A is true but R is false

Adsorption ∝ vanderwaal attraction forces 

Zc​=\(\frac{3}{8}\)​ for all natural gases.

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Concepts Used:

Adsorption

Heinrich Kayser, the German physicist was the first to coin the term adsorption. Adsorption can be explained as a surface phenomenon where particles remain attached on the top of a material. Generally, it comprises the molecules, atoms, liquid, solid in a dissolved stage, even the ions of a gas that are attached to the surface. Much to our surprise, the consequence of surface energy i.e. adsorption is present in biological, physical, chemical, and natural systems and are used in many industrial applications.