The amount of phenol adsorbed by the adsorbent can be calculated by comparing the initial amount of phenol in the solution and the final residual concentration after adsorption.
Step 1: Initial amount of phenol in the solution
The initial concentration of phenol in the solution is 100 mg/L, and the volume of the solution is 100 mL (0.1 L). Therefore, the initial amount of phenol in the solution is:
\[ \text{Initial phenol} = 100 \, \text{mg/L} \times 0.1 \, \text{L} = 10 \, \text{mg} \]
Step 2: Final amount of phenol in the solution
The residual concentration of phenol after adsorption is 30 mg/L. Therefore, the final amount of phenol in the solution is:
\[ \text{Final phenol} = 30 \, \text{mg/L} \times 0.1 \, \text{L} = 3 \, \text{mg} \]
Step 3: Amount of phenol adsorbed
The amount of phenol adsorbed is the difference between the initial and final amounts of phenol:
\[ \text{Phenol adsorbed} = 10 \, \text{mg} - 3 \, \text{mg} = 7 \, \text{mg} \]
Step 4: Amount of phenol adsorbed per gram of dry adsorbent
The mass of the dry adsorbent is 500 mg, which is 0.5 g. The amount of phenol adsorbed per gram of adsorbent is:
\[ \frac{\text{Phenol adsorbed}}{\text{Mass of adsorbent}} = \frac{7 \, \text{mg}}{0.5 \, \text{g}} = 14 \, \text{mg/g} \]
Therefore, the correct answer is: 14 mg per gram of dry adsorbent.
Consider a process with transfer function: \[ G_p = \frac{2e^{-s}}{(5s + 1)^2} \] A first-order plus dead time (FOPDT) model is to be fitted to the unit step process reaction curve (PRC) by applying the maximum slope method. Let \( \tau_m \) and \( \theta_m \) denote the time constant and dead time, respectively, of the fitted FOPDT model. The value of \( \frac{\tau_m}{\theta_m} \) is __________ (rounded off to 2 decimal places).
Given: For \( G = \frac{1}{(\tau s + 1)^2} \), the unit step output response is: \[ y(t) = 1 - \left(1 + \frac{t}{\tau}\right)e^{-t/\tau} \] The first and second derivatives of \( y(t) \) are: \[ \frac{dy(t)}{dt} = \frac{t}{\tau^2} e^{-t/\tau} \] \[ \frac{d^2y(t)}{dt^2} = \frac{1}{\tau^2} \left(1 - \frac{t}{\tau}\right) e^{-t/\tau} \]
Methanol is produced by the reversible, gas-phase hydrogenation of carbon monoxide: \[ {CO} + 2{H}_2 \rightleftharpoons {CH}_3{OH} \] CO and H$_2$ are charged to a reactor, and the reaction proceeds to equilibrium at 453 K and 2 atm. The reaction equilibrium constant, which depends only on the temperature, is 1.68 at the reaction conditions. The mole fraction of H$_2$ in the product is 0.4. Assuming ideal gas behavior, the mole fraction of methanol in the product is ____________ (rounded off to 2 decimal places).