Step 1: Understanding the Concept:
Each subshell \(l\) has \(2l+1\) orbitals with magnetic quantum numbers \(m_l\) ranging from \(-l\) to \(+l\). For every subshell (\(s, p, d, f\)), exactly one orbital has \(m_l=0\).
Step 2: Detailed Explanation:
The ground state electronic configuration of Ge (\(Z=32\)) is:
\[ 1s^2 2s^2 2p^6 3s^2 3p^6 4s^2 3d^{10} 4p^2 \]
Let's identify the completely filled orbitals with \(m_l=0\):
- \(1s^2\): One \(s\) orbital (\(m_l=0\)). Completely filled. (1)
- \(2s^2\): One \(s\) orbital (\(m_l=0\)). Completely filled. (1)
- \(2p^6\): Three \(p\) orbitals (\(m_l = -1, 0, +1\)). The \(m_l=0\) orbital is completely filled. (1)
- \(3s^2\): One \(s\) orbital (\(m_l=0\)). Completely filled. (1)
- \(3p^6\): Three \(p\) orbitals (\(m_l = -1, 0, +1\)). The \(m_l=0\) orbital is completely filled. (1)
- \(4s^2\): One \(s\) orbital (\(m_l=0\)). Completely filled. (1)
- \(3d^{10}\): Five \(d\) orbitals (\(m_l = -2, -1, 0, 1, 2\)). The \(m_l=0\) orbital is completely filled. (1)
- \(4p^2\): According to Hund's rule, the 2 electrons occupy separate orbitals (e.g., \(m_l = -1\) and \(m_l = 0\)). The orbital with \(m_l=0\) contains only 1 electron and is thus not completely filled.
Sum of completely filled orbitals with \(m_l=0\): \( 1 + 1 + 1 + 1 + 1 + 1 + 1 = 7 \).
Step 3: Final Answer:
The value of \(x\) is 7.