An ambidentate ligand is a type of ligand that can bind to a metal ion at two different donor atoms, one of which is used to form a coordinate bond at a time. These ligands contain two or more donor atoms, but only one donor atom is involved in the binding with the metal ion at a given time. An example of an ambidentate ligand is thiocyanate (\( \text{SCN}^- \)), where the sulfur or nitrogen atom can serve as the donor atom.
Thus, the correct answer is:
\[
\text{(3) Ambidentate ligand}
\]