
The problem asks us to identify the correct thermodynamic equations that describe the processes A and B shown in the given Pressure-Volume (P-V) diagram.
The key to solving this problem is to distinguish between different thermodynamic processes based on the slope of their curves on a P-V diagram.
Step 1: Analyze the slopes of the curves A and B in the P-V diagram.
The diagram shows two expansion processes (volume is increasing). We can visually inspect the steepness of the two curves. At any point of intersection with a vertical line (constant volume), curve B is steeper than curve A. Based on the concept that the adiabatic curve is steeper than the isothermal curve, we can identify the processes.
Process A: The curve is less steep. This corresponds to an isothermal process.
Process B: The curve is steeper. This corresponds to an adiabatic process.
Step 2: Evaluate the given options based on this identification.
Option (1): \( pV^\gamma = k \) for process B and \( PV = k \) for process A.
This statement is correct.
Option (2): \( PV = k \) for process B and A.
This suggests both processes are isothermal, which is incorrect as they have different slopes. This statement is incorrect.
Option (3): \( \frac{P^{\gamma-1}}{T^\gamma} = k \) for process B and \( T = k \) for process A.
This statement is also correct.
Option (4): \( \frac{T^\gamma}{P^{\gamma-1}} = k \) for process A and \( pV = k \) for process B.
This incorrectly assigns the adiabatic relation to process A and the isothermal relation to process B. This statement is incorrect.
Based on our analysis, both Option (1) and Option (3) provide correct descriptions for the processes shown in the figure.
Therefore, the correct statements are given in (1) and (3).
To determine the correct statements about the processes represented in the graph, we need to analyze the nature of processes A and B.
Process A is typically an isothermal process, which means that the temperature remains constant (\( T = \text{const} \)).
For an isothermal process, the equation \( PV = nRT \) holds true, indicating that the product of pressure and volume is constant.
Process B appears to be adiabatic since the slope is steeper than that of an isothermal process, which indicates that heat is not exchanged with the environment.
The adiabatic process is described by the equation \( PV^\gamma = \text{const} \), where \( \gamma = \frac{C_p}{C_v} \) is the ratio of specific heats.
Statements Analysis:
Statement (1): \( PV^n = k \) for process B is correct if process B follows an adiabatic path. \( PV = k \) for process A is also valid as it suggests constant temperature.
Statement (2): This statement does not hold true based on the analysis of processes A and B.
Statement (3): \( P^{n-1} = k \) for process B is valid for an adiabatic process, while \( T^n = k \) is a general representation for process A under isothermal conditions.
Statement (4): This statement is misleading; the relationship does not generally hold in the given form.
Thus, the correct statements regarding processes A and B are:
(1) and (3).

Nature of compounds TeO₂ and TeH₂ is___________ and ______________respectively.