To determine the correct statements about the processes represented in the graph, we need to analyze the nature of processes A and B.
Process A is typically an isothermal process, which means that the temperature remains constant (\( T = \text{const} \)).
For an isothermal process, the equation \( PV = nRT \) holds true, indicating that the product of pressure and volume is constant.
Process B appears to be adiabatic since the slope is steeper than that of an isothermal process, which indicates that heat is not exchanged with the environment.
The adiabatic process is described by the equation \( PV^\gamma = \text{const} \), where \( \gamma = \frac{C_p}{C_v} \) is the ratio of specific heats.
Statements Analysis:
Statement (1): \( PV^n = k \) for process B is correct if process B follows an adiabatic path. \( PV = k \) for process A is also valid as it suggests constant temperature.
Statement (2): This statement does not hold true based on the analysis of processes A and B.
Statement (3): \( P^{n-1} = k \) for process B is valid for an adiabatic process, while \( T^n = k \) is a general representation for process A under isothermal conditions.
Statement (4): This statement is misleading; the relationship does not generally hold in the given form.
Thus, the correct statements regarding processes A and B are:
(1) and (3).
The excess molar Gibbs free energy of a solution of element A and B at 1000 K is given by \( G^{XS} = -3000 X_A X_B \) J mol\(^{-1}\), where \( X_A \) and \( X_B \) are mole fractions of A and B, respectively. The activity of B in a solution of A and B containing 40 mol% of B at 1000 K is ......... (rounded off to two decimal places). Given: Ideal gas constant \( R = 8.314 \, {J mol}^{-1} {K}^{-1} \)
Consider the following cell reaction: \[ {Mg} + {Cd}^{2+} \rightleftharpoons {Mg}^{2+} + {Cd} \] The standard Gibbs free energy change for the reaction is _________ kJ (rounded off to an integer). Given: Standard oxidation potentials for the reactions with respect to the standard hydrogen electrode are:
Mg \( \rightleftharpoons \) Mg\(^{2+}\) + 2e\(^-\) \( E^\circ = 2.37 \, {V} \) Cd \( \rightleftharpoons \) Cd\(^{2+}\) + 2e\(^-\) \( E^\circ = 0.403 \, {V} \) Faraday’s constant = 96500 C mol\(^{-1}\)
If A and B are two events such that \( P(A \cap B) = 0.1 \), and \( P(A|B) \) and \( P(B|A) \) are the roots of the equation \( 12x^2 - 7x + 1 = 0 \), then the value of \(\frac{P(A \cup B)}{P(A \cap B)}\)
Consider the following sequence of reactions to produce major product (A):
The molar mass of the product (A) is g mol−1. (Given molar mass in g mol−1 of C: 12,
H: 1, O: 16, Br: 80, N: 14, P: 31)
During "S" estimation, 160 mg of an organic compound gives 466 mg of barium sulphate. The percentage of Sulphur in the given compound is %.
(Given molar mass in g mol\(^{-1}\) of Ba: 137, S: 32, O: 16)
If \(\int e^x \left( \frac{x \sin^{-1} x}{\sqrt{1-x^2}} + \frac{\sin^{-1} x}{(1-x^2)^{3/2}} + \frac{x}{1-x^2} \right) dx = g(x) + C\), where C is the constant of integration, then \(g\left( \frac{1}{2} \right)\)equals:
If 1 mM solution of ethylamine produces pH = 9, then the ionization constant (\(K_b\)) of ethylamine is \(10^{-x}\).
The value of x is (nearest integer).
The degree of ionization of ethylamine can be neglected with respect to unity.