Step 1: Analyze Each Option.
Let's evaluate each option by calculating or verifying the molar mass, common name, and chemical formula:
1. Option (1): $22.5$ — Ethyne — $ \text{C}_2\text{H}_2 $
Ethyne (acetylene) has the chemical formula $ \text{C}_2\text{H}_2 $.
Molar mass:
\[
(2 \times 12.01) + (2 \times 1.01) = 24.02 + 2.02 = 26.04 \, \text{g/mol}
\]
Given: $22.5$, which is incorrect.
2. Option (2): $292.5$ — Sulphur molecule — $ \text{S}_8 $
Molar mass:
\[
8 \times 32.07 = 256.56 \, \text{g/mol}
\]
Given: $292.5$, which is incorrect.
3. Option (3): $36.5$ — Hydrochloric acid — $ \text{HCl} $
Molar mass:
\[
1.01 + 35.45 = 36.46 \, \text{g/mol}
\]
Given: $36.5$, which is correct.
4. Option (4): $65.5$ — Nitric acid — $ \text{HNO}_3 $
Molar mass:
\[
1.01 + 14.01 + (3 \times 16.00) = 1.01 + 14.01 + 48.00 = 63.02 \, \text{g/mol}
\]
Given: $65.5$, which is incorrect.
Step 2: Final Answer.
\[
\boxed{(3) \quad 36.5 \text{-Hydrochloric acid-} \text{HCl}}
\]