Step 1: Understand Plaster of Paris.
Plaster of Paris is a form of calcium sulfate hemihydrate, which is obtained by heating gypsum ($ \text{CaSO}_4 \cdot 2\text{H}_2\text{O} $). Its chemical formula is:
\[
\text{CaSO}_4 \cdot \frac{1}{2} \text{H}_2\text{O}.
\]
Step 2: Analyze Each Option.
Option (1): $ \text{CaSO}_4 $ — Incorrect, as this is the formula for anhydrous calcium sulfate, not plaster of Paris.
Option (2): $ \text{CaSO}_4 \cdot \frac{1}{2} \text{H}_2\text{O} $ — Correct, as this matches the formula for plaster of Paris.
Option (3): $ \text{CaSO}_4 \cdot \text{H}_2\text{O} $ — Incorrect, as this is the formula for gypsum, not plaster of Paris.
Option (4): $ \text{CaSO}_3 $ — Incorrect, as this is the formula for calcium sulfite, not plaster of Paris.
Step 3: Final Answer.
\[
\boxed{(2) \quad \text{CaSO}_4 \cdot \frac{1}{2} \text{H}_2\text{O}}
\]