Step 1: Compute the initial energy stored in the capacitor.
The energy stored in a capacitor is given by:
\[
E = \frac{1}{2} C V^2.
\]
Substitute \(C = 10 \, \mu{F} = 10 \times 10^{-6} \, {F}\) and \(V = 10 \, {V}\):
\[
E_{{initial}} = \frac{1}{2} \cdot 10 \times 10^{-6} \cdot (10)^2 = 0.0005 \, {J}.
\]
Step 2: Compute the final energy stored in the capacitor.
After the switch is closed, the voltage across the capacitor is clamped to \(V_Z = 5 \, {V}\). The energy stored becomes:
\[
E_{{final}} = \frac{1}{2} \cdot 10 \times 10^{-6} \cdot (5)^2 = 0.000250 \, {J}.
\]
Step 3: Calculate the energy dissipated in the Zener diode.
The energy dissipated is the difference between the initial and final energies:
\[
E_{{dissipated}} = E_{{initial}} - E_{{final}} = 0.0005 - 0.000250 = 0.000250 \, {J}.
\]
Convert this to millijoules:
\[
E_{{dissipated}} = 0.250 \, {mJ}.
\]
Final Answer:
\[
\boxed{{0.250}}
\]