The object is projected in the \( xy \)-plane at an angle of \( 45^\circ \) with the x-axis. The velocity at any point can be written as:
\[
\vec{v} = v_0 (\cos 45^\circ \hat{i} + \sin 45^\circ \hat{j}).
\]
At the maximum height, the vertical component of the velocity becomes zero, i.e., \( v_y = 0 \), and only the horizontal component remains:
\[
v_x = v_0 \cos 45^\circ = \frac{v_0}{\sqrt{2}}.
\]
The object’s position at maximum height is given by:
\[
y = \frac{v_0^2 \sin 45^\circ \cos 45^\circ}{g} = \frac{v_0^2 \sin 90^\circ}{2g} = \frac{v_0^2}{2g}.
\]
The horizontal position at maximum height is:
\[
x = v_0 \cos 45^\circ \times \frac{v_0}{g} = \frac{v_0^2}{g\sqrt{2}}.
\]
At the maximum height, the angular momentum \( L \) with respect to the origin is given by:
\[
\vec{L} = \vec{r} \times m\vec{v}.
\]
The position vector \( \vec{r} = x \hat{i} + y \hat{j} \) and the velocity \( \vec{v} = v_x \hat{i} \) at maximum height.
The magnitude of the angular momentum is:
\[
L = m \left( x v_y - y v_x \right),
\]
where \( v_y = 0 \) and \( v_x = \frac{v_0}{\sqrt{2}} \).
Thus, the angular momentum simplifies to:
\[
L = m \left( \frac{v_0^2}{g\sqrt{2}} \times \frac{v_0}{\sqrt{2}} \right) = \frac{mv_0^3}{4\sqrt{2}g}.
\]
Since the object was projected at an angle with the x-axis, the direction of angular momentum is along the negative z-axis, due to the direction of the rotational motion.
Thus, the magnitude and direction of the angular momentum are:
\[
\boxed{\frac{mv_0^3}{4\sqrt{2}g}} { along negative z-axis}.
\]