Given: an electron (mass \(m\), charge \(-e\)) enters a uniform magnetic field \(\vec{B}=B\hat{j}\) with initial velocity \(\vec{v}=\vec{v_0}\) (where \(v_0>0\)). The de-Broglie wavelength initially is \(\lambda_0\). We need to find its wavelength after time \(t\).
The magnetic field exerts a force on the moving electron given by the Lorentz force:
\[ \vec{F} = -e(\vec{v}\times\vec{B}). \]
This force changes the direction of velocity but not its magnitude (since the magnetic force is perpendicular to \(\vec{v}\)). Hence, the speed remains constant.
The de-Broglie wavelength is given by:
\[ \lambda = \frac{h}{p} = \frac{h}{mv}. \] Since \(v\) (the magnitude of velocity) is unchanged, the de-Broglie wavelength also remains constant in time.
Step 1: Write the equation of motion:
\[ m\frac{d\vec{v}}{dt} = -e(\vec{v}\times\vec{B}). \]
The magnetic field causes circular motion with angular frequency (cyclotron frequency):
\[ \omega = \frac{eB}{m}. \]
Step 2: The magnitude of velocity remains \(v_0\), only its direction changes with time. Therefore, momentum magnitude \(p=mv_0\) remains constant.
Step 3: Hence, the de-Broglie wavelength at time \(t\) is:
\[ \lambda = \frac{h}{mv_0} = \lambda_0. \]
\[ \boxed{\lambda(t)=\lambda_0.} \]
The de-Broglie wavelength of the electron remains unchanged with time.
For a given reaction \( R \rightarrow P \), \( t_{1/2} \) is related to \([A_0]\) as given in the table. Given: \( \log 2 = 0.30 \). Which of the following is true?
| \([A]\) (mol/L) | \(t_{1/2}\) (min) |
|---|---|
| 0.100 | 200 |
| 0.025 | 100 |
A. The order of the reaction is \( \frac{1}{2} \).
B. If \( [A_0] \) is 1 M, then \( t_{1/2} \) is \( 200/\sqrt{10} \) min.
C. The order of the reaction changes to 1 if the concentration of reactant changes from 0.100 M to 0.500 M.
D. \( t_{1/2} \) is 800 min for \( [A_0] = 1.6 \) M.