An electron of a hydrogen like atom, having \(Z=4\), jumps from \(4^{\text {th }}\) energy state to \(2^{\text {nd }}\) energy state. The energy released in this process, will be :
\((\) Given Rch \(=136 eV )\)
Where \(R =\) Rydberg constant
\(c =\) Speed of light in vacuum
\(h =\) Planck's constant
Step 1: Recall the Formula for Energy Levels in Hydrogen-like Atoms
The energy of an electron in a hydrogen-like atom is given by:
\( E_n = -13.6 \frac{Z^2}{n^2} \, \text{eV} \)
where \( Z \) is the atomic number and \( n \) is the principal quantum number.
Step 2: Calculate the Energy Difference
The energy released (\( \Delta E \)) when an electron jumps from an initial state (\( n_i \)) to a final state (\( n_f \)) is given by the difference in energy levels:
\( \Delta E = E_{n_i} - E_{n_f} = 13.6 Z^2 \left( \frac{1}{n_f^2} - \frac{1}{n_i^2} \right) \, \text{eV} \)
In this case, \( Z = 4 \), \( n_i = 4 \), and \( n_f = 2 \). Substituting these values, we get:
\( \Delta E = 13.6 \times (4^2) \left( \frac{1}{2^2} - \frac{1}{4^2} \right) \, \text{eV} \)
\( \Delta E = 13.6 \times 16 \left( \frac{1}{4} - \frac{1}{16} \right) \, \text{eV} \)
\( \Delta E = 13.6 \times 16 \left( \frac{4 - 1}{16} \right) \, \text{eV} \)
\( \Delta E = 13.6 \times 16 \times \frac{3}{16} \, \text{eV} \)
\( \Delta E = 13.6 \times 3 = 40.8 \, \text{eV} \)
Conclusion: The energy released in the process is 40.8 eV (Option 1).
Given below are two statements:
Statement (I) : The dimensions of Planck’s constant and angular momentum are same.
Statement (II) : In Bohr’s model, electron revolves around the nucleus in those orbits for which angular momentum is an integral multiple of Planck’s constant.
In the light of the above statements, choose the most appropriate answer from the options given below:
A(g) $ \rightarrow $ B(g) + C(g) is a first order reaction.
The reaction was started with reactant A only. Which of the following expression is correct for rate constant k ?
$\mathrm{KMnO}_{4}$ acts as an oxidising agent in acidic medium. ' X ' is the difference between the oxidation states of Mn in reactant and product. ' Y ' is the number of ' d ' electrons present in the brown red precipitate formed at the end of the acetate ion test with neutral ferric chloride. The value of $\mathrm{X}+\mathrm{Y}$ is _______ .
Niels Bohr introduced the atomic Hydrogen model in 1913. He described it as a positively charged nucleus, comprised of protons and neutrons, surrounded by a negatively charged electron cloud. In the model, electrons orbit the nucleus in atomic shells. The atom is held together by electrostatic forces between the positive nucleus and negative surroundings.
Read More: Bohr's Model of Hydrogen Atom
A hydrogen-like atom consists of a tiny positively-charged nucleus and an electron revolving around the nucleus in a stable circular orbit.
If 'e,' 'm,' and 'v' be the charge, mass, and velocity of the electron respectively, 'r' be the radius of the orbit, and Z be the atomic number, the equation for the radii of the permitted orbits is given by r = n2 xr1, where 'n' is the principal quantum number, and r1 is the least allowed radius for a hydrogen atom, known as Bohr's radius having a value of 0.53 Å.
The Bohr Model was an important step in the development of atomic theory. However, it has several limitations.