[Fe(H2O)3Cl3] → Outer-orbital complex
K3[Fe(CN)6] → Inner-orbital complex
[Co(NH3)6]Cl3 → Inner-orbital complex
Since CN– is a strong field ligand than NH3. Hence K3[Fe(CN)6] is the inner-orbital complex that absorbs light at shortest wavelength.
Fe(III) → valence shell configuration 3d5
Since CN– will do pairing, so unpaired electron = 1
\(μ=\sqrt{1(1+2)}=\sqrt3BM=2BM\)
List-I-Complex | List-II-CFSE | ||
A | [Cu(NH3)6]2+ | I | -0.6 |
B | [Ti(H2O)6]3+ | II | -2.0 |
C | [Fe(CN)6]3− | III | -1.2 |
D | [NiF6]4- | IV | -0.4 |
Ordinary Differential Equations is an equation that indicates the relation of having one independent variable x, and one dependent variable y, along with some of its other derivatives.
\(F(\frac{dy}{dt},y,t) = 0\)
A partial differential equation is a type, in which the equation carries many unknown variables with their partial derivatives.
It is the linear polynomial equation in which derivatives of different variables exist. Linear Partial Differential Equation derivatives are partial and function is dependent on the variable.
When the degree of f(x,y) and g(x,y) is the same, it is known to be a homogeneous differential equation.
\(\frac{dy}{dx} = \frac{a_1x + b_1y + c_1}{a_2x + b_2y + c_2}\)
Read More: Differential Equations