Step 1: Calculate Work Done from A to B: - Since the process from A to B is linear on the pressure-volume diagram, the work done WAB can be calculated as the area under the line AB. - The average pressure from A to B is \( \frac{8000 + 4000}{2} = 6000 \, \text{dyne/cm}^2 \). - The volume change from A to B is 4 m3.
\( W_{AB} = \text{Average Pressure} \times \text{Change in Volume} \)
\( W_{AB} = 6000 \times 4 \, \text{dyne/cm}^2 \times \text{m}^3 \)
Step 2: Convert Units: - Convert dyne/cm2 to N/m2 by using 1 dyne/cm2 = 10-5 N/m2.
\( W_{AB} = 6000 \times 10^{-5} \times 4 \, \text{J} = 800 \, \text{J} \)
Step 3: Calculate Work Done from B to C: - From B to C, the process is isobaric (constant pressure), so work done WBC = Pressure × Change in Volume. - The pressure at B and C is 4000 dyne/cm2. - Volume change from B to C is −4 m3 (since the volume is reducing).
\( W_{BC} = 4000 \times (-4) \times 10^{-5} \, \text{J} = -800 \, \text{J} \)
Step 4: Total Work Done:
\( W_{total} = W_{AB} + W_{BC} = 800 - 800 = 0 \, \text{J} \)
So, the correct answer is: 0J.
The excess molar Gibbs free energy of a solution of element A and B at 1000 K is given by \( G^{XS} = -3000 X_A X_B \) J mol\(^{-1}\), where \( X_A \) and \( X_B \) are mole fractions of A and B, respectively. The activity of B in a solution of A and B containing 40 mol% of B at 1000 K is ......... (rounded off to two decimal places). Given: Ideal gas constant \( R = 8.314 \, {J mol}^{-1} {K}^{-1} \)
Consider the following cell reaction: \[ {Mg} + {Cd}^{2+} \rightleftharpoons {Mg}^{2+} + {Cd} \] The standard Gibbs free energy change for the reaction is _________ kJ (rounded off to an integer). Given: Standard oxidation potentials for the reactions with respect to the standard hydrogen electrode are:
Mg \( \rightleftharpoons \) Mg\(^{2+}\) + 2e\(^-\) \( E^\circ = 2.37 \, {V} \) Cd \( \rightleftharpoons \) Cd\(^{2+}\) + 2e\(^-\) \( E^\circ = 0.403 \, {V} \) Faraday’s constant = 96500 C mol\(^{-1}\)