The first law of thermodynamics states that:
\( \Delta Q = \Delta U + \Delta W \)
We can also express this in terms of rates as:
\( \frac{dQ}{dt} = \frac{dU}{dt} + \frac{dW}{dt} \)
We are given the rate of heat transfer to the system as \( \frac{dQ}{dt} = 1000 \, \text{W} \) and the rate of work done by the system as \( \frac{dW}{dt} = 200 \, \text{W} \). Substituting these values into the equation:
\( 1000 \, \text{W} = \frac{dU}{dt} + 200 \, \text{W} \)
Rearrange the equation to solve for the rate of change of internal energy:
\( \frac{dU}{dt} = 1000 \, \text{W} - 200 \, \text{W} = 800 \, \text{W} \)
The rate at which the internal energy of the system increases is 800 W (Option 3).
Match List - I with List - II.

1.24 g of $ {AX}_2 $ (molar mass 124 g mol$^{-1}$) is dissolved in 1 kg of water to form a solution with boiling point of 100.105$^\circ$C, while 2.54 g of $ {AY}_2 $ (molar mass 250 g mol$^{-1}$) in 2 kg of water constitutes a solution with a boiling point of 100.026$^\circ$C. $ K_{b(H_2O)} = 0.52 \, \text{K kg mol}^{-1} $. Which of the following is correct?
For the reaction:

The correct order of set of reagents for the above conversion is :
Let \( a \in \mathbb{R} \) and \( A \) be a matrix of order \( 3 \times 3 \) such that \( \det(A) = -4 \) and \[ A + I = \begin{bmatrix} 1 & a & 1 \\ 2 & 1 & 0 \\ a & 1 & 2 \end{bmatrix} \] where \( I \) is the identity matrix of order \( 3 \times 3 \).
If \( \det\left( (a + 1) \cdot \text{adj}\left( (a - 1) A \right) \right) \) is \( 2^m 3^n \), \( m, n \in \{ 0, 1, 2, \dots, 20 \} \), then \( m + n \) is equal to:
Rate law for a reaction between $A$ and $B$ is given by $\mathrm{R}=\mathrm{k}[\mathrm{A}]^{\mathrm{n}}[\mathrm{B}]^{\mathrm{m}}$. If concentration of A is doubled and concentration of B is halved from their initial value, the ratio of new rate of reaction to the initial rate of reaction $\left(\frac{\mathrm{r}_{2}}{\mathrm{r}_{1}}\right)$ is