The reagent that gives a brilliant red precipitate with Nickel ions (\( \text{Ni}^{2+} \)) in a basic medium is dimethyl glyoxime (dmg). When \( \text{Ni}^{2+} \) reacts with dimethyl glyoxime, it forms a complex that produces a bright red precipitate. The reaction is as follows:
\(\text{Ni}^{2+} + \text{dmg} \rightarrow [\text{Ni}(\text{dmg})_2] \, \, (\text{Rosy red/Bright Red precipitate})\)
Thus, the correct answer is dimethyl glyoxime.
The Correct Answer is: dimethyl glyoxime
List - I(Test/reagent) | List - II(Radical identified) |
---|---|
(A) Lake Test | (I) NO3− |
(B) Nessler’s Reagent | (II) Fe3+ |
(C) Potassium sulphocyanide | (III) Al3+ |
(D) Brown Ring Test | (IV) NH4+ |
List - ISolid salt treated with dil. H2SO4 | List - IIAnion detected |
---|---|
(A) effervescence of colourless gas | (I) NO2− |
(B) gas with smell of rotten egg | (II) CO32− |
(C) gas with pungent smell | (III) S2− |
(D) brown fumes | (IV) SO23− |