Step 1: Understand the decay formula.
The number of nuclei remaining in a radioactive sample after time \( t \) is given by the equation:
\[ N(t) = N_0 \left( \frac{1}{2} \right)^{\frac{t}{T}} \] where: \( N_0 \) is the initial number of nuclei, \( t \) is the time elapsed, \( T \) is the half-life of the substance.
Step 2: Use the given values for A and B.
For sample A, \( T_A = 12 \) hours, For sample B, \( T_B = 16 \) hours, After 48 hours, we calculate the remaining number of nuclei in each sample using the decay formula.
For sample A: \[ N_A(48) = N_{A0} \left( \frac{1}{2} \right)^{\frac{48}{12}} = N_{A0} \left( \frac{1}{2} \right)^4 = N_{A0} \times \frac{1}{16} \] For sample B: \[ N_B(48) = N_{B0} \left( \frac{1}{2} \right)^{\frac{48}{16}} = N_{B0} \left( \frac{1}{2} \right)^3 = N_{B0} \times \frac{1}{8} \]
Step 3: Conclusion.
After 48 hours, the ratio of \( N_A(48) \) to \( N_B(48) \) becomes: \[ \frac{N_A(48)}{N_B(48)} = \frac{N_{A0} \times \frac{1}{16}}{N_{B0} \times \frac{1}{8}} = \frac{1}{2} \] Thus, the ratio of the number of nuclei becomes 1:1.
Conclusion:
The correct answer is (A) 1:1.
At 15 atm pressure, $ \text{NH}_3(g) $ is being heated in a closed container from 27°C to 347°C and as a result, it partially dissociates following the equation: $ 2\text{NH}_3(g) \rightleftharpoons \text{N}_2(g) + 3\text{H}_2(g) $ If the volume of the container remains constant and pressure increases to 50 atm, then calculate the percentage dissociation of $ \text{NH}_3(g) $
If equilibrium constant for the equation $ A_2 + B_2 \rightleftharpoons 2AB \quad \text{is} \, K_p, $ then find the equilibrium constant for the equation $ AB \rightleftharpoons \frac{1}{2} A_2 + \frac{1}{2} B_2. $
Consider the following reaction: $ \text{CO}(g) + \frac{1}{2} \text{O}_2(g) \rightarrow \text{CO}_2(g) $ At 27°C, the standard entropy change of the process becomes -0.094 kJ/mol·K. Moreover, standard free energies for the formation of $ \text{CO}_2(g) $ and $ \text{CO}(g) $ are -394.4 and -137.2 kJ/mol, respectively. Predict the nature of the above chemical reaction.