Extrinsic semiconductors are made by doping pure or intrinsic semiconductors with suitable impurity. There are two types of dopants used in doping, Si or Ge, and using them p-type and n-type semiconductors can be obtained. A p-n junction is the basic building block of many semiconductor devices. Two important processes occur during the formation of a p-n junction: diffusion and drift. When such a junction is formed, a ’depletion layer’ is created consisting of immobile ion-cores. This is responsible for a junction potential barrier. The width of a depletion layer and the height of potential barrier changes when a junction is forward-biased or reverse-biased. A semiconductor diode is basically a p-n junction with metallic contacts provided at the ends for application of an external voltage. Using diodes, alternating voltages can be rectified.
At 15 atm pressure, $ \text{NH}_3(g) $ is being heated in a closed container from 27°C to 347°C and as a result, it partially dissociates following the equation: $ 2\text{NH}_3(g) \rightleftharpoons \text{N}_2(g) + 3\text{H}_2(g) $ If the volume of the container remains constant and pressure increases to 50 atm, then calculate the percentage dissociation of $ \text{NH}_3(g) $
If equilibrium constant for the equation $ A_2 + B_2 \rightleftharpoons 2AB \quad \text{is} \, K_p, $ then find the equilibrium constant for the equation $ AB \rightleftharpoons \frac{1}{2} A_2 + \frac{1}{2} B_2. $
Consider the following reaction: $ \text{CO}(g) + \frac{1}{2} \text{O}_2(g) \rightarrow \text{CO}_2(g) $ At 27°C, the standard entropy change of the process becomes -0.094 kJ/mol·K. Moreover, standard free energies for the formation of $ \text{CO}_2(g) $ and $ \text{CO}(g) $ are -394.4 and -137.2 kJ/mol, respectively. Predict the nature of the above chemical reaction.